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Merck
CN

D129208

甲苯-3,4-二硫酚

technical grade, 90%

别名:

3,4-二巯基甲苯, 3,4-甲苯二硫醇, 4-甲基邻二苯硫酚

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关于此项目

线性分子式:
CH3C6H3(SH)2
化学文摘社编号:
分子量:
156.27
Beilstein:
1635270
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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等级

technical grade

质量水平

方案

90%

表单

powder

沸点

135-137 °C/17 mmHg (lit.)

mp

30-33 °C (lit.)

密度

1.179 g/mL at 25 °C (lit.)

储存温度

−20°C

SMILES字符串

Cc1ccc(S)c(S)c1

InChI

1S/C7H8S2/c1-5-2-3-6(8)7(9)4-5/h2-4,8-9H,1H3

InChI key

NIAAGQAEVGMHPM-UHFFFAOYSA-N

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应用

在双核二硫酚金(I) 配合物研究中用于生成相应的二硫酚配体。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

235.4 °F - closed cup

闪点(°C)

113 °C - closed cup

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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Inorganic Chemistry, 32, 1749-1749 (1993)
Marcos A Oliveira et al.
Biochemistry, 49(15), 3317-3326 (2010-03-20)
The enzymatic activity of thioredoxin reductase enzymes is endowed by at least two redox centers: a flavin and a dithiol/disulfide CXXC motif. The interaction between thioredoxin reductase and thioredoxin is generally species-specific, but the molecular aspects related to this phenomenon
Heather L Tienson et al.
Molecular biology of the cell, 20(15), 3481-3490 (2009-05-30)
Mia40 and Erv1 execute a disulfide relay to import the small Tim proteins into the mitochondrial intermembrane space. Here, we have reconstituted the oxidative folding pathway in vitro with Tim13 as a substrate and determined the midpoint potentials of Mia40
Novel regulators in photosynthetic redox control of plant metabolism and gene expression.
Karl-Josef Dietz et al.
Plant physiology, 155(4), 1477-1485 (2011-01-06)
Ulf Ryde et al.
Journal of the American Chemical Society, 132(13), 4512-4513 (2010-03-17)
The active site of the [FeFe] hydrogenases contains two Fe ions bound to one Cys ligand, three CO molecules, two CN(-) ions, and a dithiolate ligand. The nature of the last of these has been much discussed, and it has

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