质量水平
检测方案
98%
形式
crystals
mp
76-78 °C (lit.)
SMILES字符串
CCNC(=S)NCC
InChI
1S/C5H12N2S/c1-3-6-5(8)7-4-2/h3-4H2,1-2H3,(H2,6,7,8)
InChI key
FLVIGYVXZHLUHP-UHFFFAOYSA-N
基因信息
human ... EPHX2(2053)
mouse ... Ephx2(13850)
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应用
N,N′-Diethylthiourea can be used as a reactant to prepare:
- 3,5-Diethyltetrahydro-4-thioxo-1,3,5-triazine-1(2H)-propanoic acid by condensation reaction with formaldehyde and β-alanine.
- Methyl 3-ethyl-2-(ethylimino)-3,4-dihydro-4-oxo-2H-1,3-thiazine-6-carboxylate by one-pot reaction with dimethyl acetylenedicarboxylate in the presence of triphenylphosphine catalyst.
- 2-(Ethylimino)-3-ethyl-thiazolidin-4-one by cyclization reaction with 2-chloroacetic acid.
- 3-Ethyl-2-(ethylimino)-4-oxo-5-thiazolidineacetamide by condensation reaction with maleimides via Michael-type reaction.
警示用语:
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Skin Sens. 1B
WGK
WGK 2
闪点(°F)
366.8 °F
闪点(°C)
186 °C
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Ph 3 P-mediated one-pot synthesis of functionalized 3, 4-dihydro-2 H-1, 3-thiazines from N, N?-dialkylthioureas and activated acetylenes in water
Monatshefte fur Chemie / Chemical Monthly, 141(2), 229-232 (2010)
An eco-friendly preparation of 2-iminothiazolidin-4-ones derivatives
Organic preparations and procedures international, 44(2), 184-186 (2012)
Aminomethylation of Symmetric Dialkylthioureas with Formaldehyde and Amino Acids
Russ. J. Gen. Chem., 90(11), 2043-2047 (2020)
Efficient 2-amino-2-thiazolin-4-ones or 2-iminothiazolidin-4-ones formation from thioureas and maleimides under solvent-free conditions
Heterocycles, 71(5), 1053-1058 (2007)
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