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经验公式(希尔记法):
C3Cl3N3
化学文摘社编号:
分子量:
184.41
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-614-9
Beilstein/REAXYS Number:
124246
MDL number:
产品名称
三聚氯氰, 99%
InChI key
MGNCLNQXLYJVJD-UHFFFAOYSA-N
InChI
1S/C3Cl3N3/c4-1-7-2(5)9-3(6)8-1
SMILES string
Clc1nc(Cl)nc(Cl)n1
vapor density
6.36 (vs air)
vapor pressure
0.8 mmHg ( 62.2 °C)
assay
99%
form
powder
bp
190 °C (lit.)
mp
145-147 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
三聚氰胺可用作以下应用的试剂:
此外,在ZnCl2存在的情况下,还可作为酮肟转化成酰胺的Beckmann重排催化剂。
- 从羧酸和叠氮化钠制备酰基叠氮。
- 将羧酸、N-Boc、 N-Cbz和N-Fmoc氨基酸转化为相应的醇。
- 通过替代Swern氧化反应将醇类转化为相应的羰基化合物。
此外,在ZnCl2存在的情况下,还可作为酮肟转化成酰胺的Beckmann重排催化剂。
用于醇转化为氯化物的试剂,用于微生物和酶的固化。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1A - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 1
flash_point_f
>392.0 °F - closed cup
flash_point_c
> 200 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Sanjay K Singh et al.
Frontiers in immunology, 11, 1812-1812 (2020-09-10)
C-reactive protein (CRP), a component of the innate immune system, is an antipneumococcal plasma protein. Human CRP has been shown to protect mice against infection with lethal doses of Streptococcus pneumoniae by decreasing bacteremia. in vitro, CRP binds to phosphocholine-containing
A mild and efficient alternative to the classical Swern oxidation.
L De Luca et al.
The Journal of organic chemistry, 66(23), 7907-7909 (2001-11-10)
Yoshiro Furuya et al.
Journal of the American Chemical Society, 127(32), 11240-11241 (2005-08-11)
The first general organocatalytic Beckmann rearrangement of ketoximes into amides has been realized by the catalytic use of cyanuric chloride. Furthermore, acids such as HCl and ZnCl2 are effective as cocatalysts with cyanuric chloride. For example, azacyclotridecan-2-one, which is synthetically
Synthesis of acyl azides from carboxylic acids using cyanuric chloride
Bandgar BP and Pandit SS
Tetrahedron Letters, 43(18), 3413-3414 (2002)
J. Mol. Catal., 80, 269-269 (1993)
商品
Collagen molecules play a critical role in tissue architecture and strength, and in cell-matrix interactions as insoluble ligands to regulate the diverse phenotypic activities of cells.
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