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线性分子式:
CH3CH=CHCH2OH
化学文摘社编号:
分子量:
72.11
NACRES:
NA.22
UNSPSC Code:
12352100
PubChem Substance ID:
EC Number:
228-086-7
Beilstein/REAXYS Number:
1361395
MDL number:
Assay:
96%
Form:
liquid
InChI key
WCASXYBKJHWFMY-NSCUHMNNSA-N
InChI
1S/C4H8O/c1-2-3-4-5/h2-3,5H,4H2,1H3/b3-2+
SMILES string
C\C=C\CO
assay
96%
form
liquid
Quality Level
bp
121-122 °C (lit.)
density
0.845 g/mL at 25 °C (lit.)
Application
巴豆醇可用作合成 14-氮杂喜树碱和 10,11-亚甲基二氧基-14-氮杂喜树碱等抗肿瘤药的起始原料。它也可以用作盘皮海绵内酯全合成中的前体。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
93.2 °F - closed cup
flash_point_c
34 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Synthesis of optically active β-alkyl aspartate via [3, 3] sigmatropic rearrangement of α-acyloxytrialkylsilane.
Sakaguchi K, et al.
Tetrahedron Letters, 45(30), 5869-5872 (2004)
Synthesis of 14-azacamptothecin, a water-soluble topoisomerase I poison.
Rahier N J, et al.
Organic Letters, 7(5), 835-837 (2005)
Darby R Schmidt et al.
Organic letters, 5(19), 3535-3537 (2003-09-12)
[structure: see text] A synthesis of the C(15)-C(30) fragment of Dolabelides A and B has been achieved. The recently developed asymmetric silane alcoholysis and tandem silylformylation-crotylsilylation reactions were used as the key steps to establish the C(23)-C(27) 1,5-syn-diol. In addition
Frank R Fontaine et al.
Chemical research in toxicology, 15(8), 1051-1058 (2002-08-20)
Recent confirmation that the toxic unsaturated aldehyde crotonaldehyde (CA) contributes to protein damage during lipid peroxidation confers interest on the molecular actions of this substance. However, since a plethora of structurally related aldehydes form during membrane oxidation, clarifying the toxicological
Evaluation of the role of acetaldehyde in the actions of ethanol on gluconeogenesis by comparison with the effects of crotonol and crotonaldehyde.
A I Cederbaum et al.
Alcoholism, clinical and experimental research, 6(1), 100-109 (1982-01-01)
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