蒸汽密度
3.12 (vs air)
质量水平
检测方案
99%
形式
liquid
自燃温度
896 °F
expl. lim.
8.1 %
折射率
n20/D 1.4753 (lit.)
bp
138 °C (lit.)
mp
−14 °C (lit.)
密度
1.08 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
ClCC(=C)CCl
InChI
1S/C4H6Cl2/c1-4(2-5)3-6/h1-3H2
InChI key
XJFZOSUFGSANIF-UHFFFAOYSA-N
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应用
3-氯-2-氯甲基-1-丙烯可用于合成 2,11-双(亚甲基)精胺、精胺氧化酶的抑制剂和共轭聚合物的支链侧链。它也可用于(−)-诱杀烯醇全合成过程中的分子间[2+2]光环加成反应。
警示用语:
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
96.8 °F
闪点(°C)
36 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Synthesis of 2, 11-bis (methylidene) spermine, a new inhibitor of spermine oxidase.
Russian Journal of Bioorganic Chemistry, 42(4), 423-427 (2016)
Synthesis of well-defined three-and four-armed cage-shaped polymers via ?topological conversion? from trefoil-and quatrefoil-shaped polymers.
Macromolecules, 50(1), 97-106 (2016)
Diketopyrrolopyrrole?based Conjugated Polymers Bearing Branched Oligo (Ethylene Glycol) Side Chains for Photovoltaic Devices.
Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 128(35), 10532-10536 (2016)
Enantioselective Intermolecular [2+ 2] Photocycloaddition Reaction of Cyclic Enones and Its Application in a Synthesis of (−)-Grandisol.
Journal of the American Chemical Society, 140(9), 3228-3231 (2018)
Science advances, 4(8), eaat4634-eaat4634 (2018-08-29)
Liquid crystalline (LC) elastomers (LCEs) enable large-scale reversible shape changes in polymeric materials; however, they require intensive, irreversible programming approaches in order to facilitate controllable actuation. We have implemented photoinduced dynamic covalent chemistry (DCC) that chemically anneals the LCE toward
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