C22415
4-氯苯胺
98%
别名:
1-Amino-4-chlorobenzene, 4-Chlorophenylamine, p-Chloroaniline
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关于此项目
线性分子式:
ClC6H4NH2
化学文摘社编号:
分子量:
127.57
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-401-0
Beilstein/REAXYS Number:
471359
MDL number:
产品名称
4-氯苯胺, 98%
InChI key
QSNSCYSYFYORTR-UHFFFAOYSA-N
InChI
1S/C6H6ClN/c7-5-1-3-6(8)4-2-5/h1-4H,8H2
SMILES string
Nc1ccc(Cl)cc1
vapor density
4.4 (vs air)
vapor pressure
0.15 mmHg ( 25 °C)
assay
98%
form
chips
crystals or chunks
bp
232 °C (lit.)
mp
67-70 °C (lit.)
Quality Level
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Application
4-氯苯胺可用于：
- 超声作用下通过烯丙基化形成N-烯丙基-4-氯苯胺，一种含吲哚和二氢吲哚核的生物活性化合物的前体。
- 与环戊二烯进行Povarov反应生成C-2脂肪族取代四氢喹啉。
- 与醛和环酮进行曼尼希反应生成β-氨基羰基化合物。
- 在硝酸胍的存在下硝化形成4-氯-3-硝基苯胺。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Skin Sens. 1
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
248.0 °F - closed cup
flash_point_c
120.0 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Factorial study to assess an ultrasonic methodology for the allylation of 4-chloroaniline
Nascimento LFS and Fernandes JPS
Green Processing and Synthesis, 6(2), 203-209 (2017)
Guanidinium nitrate: a novel reagent for aryl nitrations
Ramana MMV, et al.
Tetrahedron Letters, 45(47), 8681-8683 (2004)
Highly efficient one-pot, three-component Mannich reaction catalysed by boric acid and glycerol in water with major `syn?diastereoselectivity
Mukhopadhyay C, et al.
Tetrahedron Letters, 50(29), 4246-4250 (2009)
Lanthanide (III)-catalyzed multi-component aza-Diels-Alder reaction of aliphatic N-arylaldimines with cyclopentadiene.
Powell DA and Batey RA.
Tetrahedron Letters, 44(41), 7569-7573 (2003)
Brian J Rasimick et al.
Journal of endodontics, 34(12), 1521-1523 (2008-11-26)
The combination of chlorhexidine and EDTA produces a white precipitate. The aim of this study was to determine if the precipitate involves the chemical degradation of chlorhexidine. The precipitate was produced and redissolved in a known amount of dilute trifluoroacetic
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