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Merck
CN

C2204

Sigma-Aldrich

ε-己内酰胺

99%

别名:

2-酮基六亚基亚胺, 环己酮异肟

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About This Item

经验公式(希尔记法):
C6H11NO
CAS号:
分子量:
113.16
Beilstein:
106934
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽压

<0.01 mmHg ( 20 °C)

质量水平

检测方案

99%

形式

crystals

自燃温度

707 °F

expl. lim.

8 %

bp

136-138 °C/10 mmHg (lit.)

mp

68-71 °C (lit.)

SMILES字符串

O=C1CCCCCN1

InChI

1S/C6H11NO/c8-6-4-2-1-3-5-7-6/h1-5H2,(H,7,8)

InChI key

JBKVHLHDHHXQEQ-UHFFFAOYSA-N

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应用

ε-己内酰胺可用作开环聚合生产尼龙-6反应的前体。它还可在阴离子催化剂的存在下,通过ε己内酰胺微波辐照合成聚(ε己内酰胺-co-ε-己内酯)。

象形图

Exclamation mark

警示用语:

Warning

危险分类

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

305.6 °F

闪点(°C)

152 °C

个人防护装备

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Microwave syntheses of poly (?-caprolactam-co-?-caprolactone)
Fang X, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 38(8), 1379-1390 (2000)
Design of a ?green? one-step catalytic production of ?-caprolactam (precursor of nylon-6)
Thomas JM and Raja R
Proceedings of the National Academy of Sciences of the USA, 102(39), 13732-13736 (2005)
?-Caprolactam: New by-product free synthesis routes
Dahlhoff, G, et al.
Catalysis Reviews: Science and Engineering, 43(4), 381-441 (2001)
Ibrahim I Ozturk et al.
Journal of inorganic biochemistry, 109, 57-65 (2012-03-02)
Three new antimony(III) halide complexes (SbX(3), X=Cl, Br and I) with the heterocyclic thione ω-thiocaprolactam (1-azacycloheptane-2-thione, (Hthcl)) of formulae {[SbCl(2)(μ(2)-Cl)(Hthcl)(2)](n)} (1), {[(SbBr(2)(μ(2)-Br)(Hthcl)(2))(2)]} (2) and {[(SbI(2)(μ(2)-I)(Hthcl)(2))(2)]} (3) were synthesized from the reaction of antimony(III) halides with ω-thiocaprolactam in 1:2 stoichiometry. The
Juliana S Félix et al.
Analytical and bioanalytical chemistry, 403(10), 2869-2882 (2012-04-25)
Adhesives used in food packaging to glue different materials can provide several substances as potential migrants, and the identification of potential migrants and migration tests are required to assess safety in the use of adhesives. Solid-phase microextraction in headspace mode

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