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Merck
CN

C2204

Sigma-Aldrich

ε-己内酰胺

99%

别名:

2-酮基六亚基亚胺, 环己酮异肟

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About This Item

经验公式(希尔记法):
C6H11NO
CAS号:
分子量:
113.16
Beilstein:
106934
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽压

<0.01 mmHg ( 20 °C)

质量水平

方案

99%

表单

crystals

自燃温度

707 °F

expl. lim.

8 %

沸点

136-138 °C/10 mmHg (lit.)

mp

68-71 °C (lit.)

SMILES字符串

O=C1CCCCCN1

InChI

1S/C6H11NO/c8-6-4-2-1-3-5-7-6/h1-5H2,(H,7,8)

InChI key

JBKVHLHDHHXQEQ-UHFFFAOYSA-N

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应用

ε-己内酰胺可用作开环聚合生产尼龙-6反应的前体。它还可在阴离子催化剂的存在下,通过ε己内酰胺微波辐照合成聚(ε己内酰胺-co-ε-己内酯)。

象形图

Exclamation mark

警示用语:

Warning

危险分类

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

305.6 °F - closed cup

闪点(°C)

152 °C - closed cup

个人防护装备

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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?-Caprolactam: New by-product free synthesis routes
Dahlhoff, G, et al.
Catalysis Reviews: Science and Engineering, 43(4), 381-441 (2001)
Design of a ?green? one-step catalytic production of ?-caprolactam (precursor of nylon-6)
Thomas JM and Raja R
Proceedings of the National Academy of Sciences of the USA, 102(39), 13732-13736 (2005)
Microwave syntheses of poly (?-caprolactam-co-?-caprolactone)
Fang X, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 38(8), 1379-1390 (2000)
Georgeta Voicu et al.
International journal of pharmaceutics, 446(1-2), 63-69 (2013-02-14)
Here, we report the fabrication of a novel ε-caprolactam-silica (ε-SiO2) network and assessed its biocompatibility and ability to improve the antimicrobial activity of kanamycin. The results of the quantitative antimicrobial assay demonstrate that the obtained ε-SiO2 network has efficiently improved
Ahmad Bitar et al.
Journal of biomedical nanotechnology, 8(5), 709-719 (2012-08-15)
Temperature and glucose sensitive microgels were prepared via radical precipitation polymerization, using N-vinylcaprolactam (NVCL) as the main monomer, N,N-methylenebisacrylamide (MBA) as a crosslinker, V50 as initiator and 4-vinylphenylboronic acid (VPBA) as a functional monomer. The LCST of homopoly (NVCL) was

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