推荐产品
质量水平
检测方案
≥80%
形式
powder
运输
dry ice
储存温度
−20°C
SMILES字符串
O[C@@H]1C=CC(=C[C@H]1OC(=C)C(O)=O)C(O)=O
InChI
1S/C10H10O6/c1-5(9(12)13)16-8-4-6(10(14)15)2-3-7(8)11/h2-4,7-8,11H,1H2,(H,12,13)(H,14,15)/t7-,8-/m1/s1
InChI key
WTFXTQVDAKGDEY-HTQZYQBOSA-N
应用
分支酸是一种代谢物,通常用于研究分支酸-预苯酯重排和合成分支酸衍生物。
通过莽草酸途径生物合成芳香氨基酸的中间体。
警示用语:
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 1B - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
个人防护装备
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Organic & biomolecular chemistry, 8(15), 3534-3542 (2010-06-10)
Several 2-amino-4-carboxypyridine, 4- and 5-carboxypyridone-based compounds were prepared and tested against three members of the chorismate-utilising enzyme family, anthranilate synthase, isochorismate synthase and salicylate synthase. Most compounds exhibited low micromolar inhibition of these three enzymes. The most potent inhibitor was
Diversity-oriented production of metabolites derived from chorismate and their use in organic synthesis.
Angewandte Chemie (International ed. in English), 50(34), 7781-7786 (2011-07-09)
Of two make one: the biosynthesis of phenazines.
Chembiochem : a European journal of chemical biology, 10(14), 2295-2304 (2009-08-07)
Journal of the American Chemical Society, 131(44), 16156-16161 (2009-10-20)
The isochorismate pyruvate lyase (IPL) from Pseudomonas aeruginosa, designated as PchB, catalyzes the transformation of isochorismate into pyruvate and salicylate, but it also catalyzes the rearrangement of chorismate into prephenate, suggesting that both reactions may proceed by a pericyclic mechanism.
Stabilization of the transition state of the chorismate-prephenate rearrangement: An ab initio study of enzyme and antibody catalysis.
Journal of the American Chemical Society, 117(47), 11628-11639 (1995)
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