推荐产品
蒸汽压
40 mmHg ( 96 °C)
质量水平
产品线
ReagentPlus®
方案
99%
表单
crystals
沸点
190 °C (lit.)
mp
88-90 °C (lit.)
SMILES字符串
BrC(Br)(Br)Br
InChI
1S/CBr4/c2-1(3,4)5
InChI key
HJUGFYREWKUQJT-UHFFFAOYSA-N
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一般描述
四溴甲烷可在有价化学品的合成中充当介质、催化剂和试剂。
应用
四溴甲烷可用于以下用途：
- 作为转移剂用于甲基丙烯酸甲酯和 p -二乙烯基苯的共聚合，形成可溶的交联聚合物。
- 作为催化剂，在无金属条件下，由苯甲醇进行好氧光氧化合成芳香酯。
- 铁化合物催化下金刚烷及其衍生物的溴代反应。
法律信息
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
危险化学品
Preparation of soluble microgel by the copolymerization of methylmethacrylate with p?divinylbenzene in the presence of tetrabromomethane.
Chen H
Journal of Polymer Science Part A: Polymer Chemistry, 22(9), 2123-2130 (1984)
Recent advances in the application of tetrabromomethane in organic synthesis
Kumar S, et al.
Inorganic chemistry frontiers, 8(15), 4288-4314 (2021)
Bromination of adamantane and its derivatives with tetrabromomethane catalyzed by iron compounds.
Khusnutdinov RI
Russ. J. Org. Chem., 51(2), 184-187 (2015)
Aerobic oxidative esterification of benzyl alcohols with catalytic tetrabromomethane under visible light irradiation.
Nobuta T
Tetrahedron Letters, 53(39), 5306-5308 (2012)
Wendan Cheng et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(26), 6880-6887 (2006-06-23)
Electronic origin for nonresonant enhancement of nonlinear optical response in the complexes formed from tetraalkylammonium halide and carbon tetrabromide is provided in view of electrostatic potentials of intermolecular donor (halide ion)-acceptor (CBr(4)). The calculated electrostatic potentials of donor-acceptor range from
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