C0267
氯乙酰胺
≥98%
别名:
Chloracetamide, alpha-Chloroacetamide
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线性分子式:
ClCH2CONH2
化学文摘社编号:
分子量:
93.51
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-174-2
Beilstein/REAXYS Number:
878191
MDL number:
Assay:
≥98%
Form:
powder
产品名称
氯乙酰胺, ≥98%
InChI
1S/C2H4ClNO/c3-1-2(4)5/h1H2,(H2,4,5)
InChI key
VXIVSQZSERGHQP-UHFFFAOYSA-N
SMILES string
NC(=O)CCl
vapor pressure
0.05 mmHg ( 20 °C)
assay
≥98%
form
powder
mp
116-118 °C (lit.)
Quality Level
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Application
2-氯乙酰胺可作为合成以下物质的反应物：
- 通过4-氯-1H-喹啉-2-酮的o烷基化和随后的Smiles重排反应合成2-氨基-4-氯喹啉。
- 在存在碱性碳酸钾的条件下，通过与羟基苯甲醛反应合成2-(甲酰基芳氧基)乙酰胺
- 通过三氟甲磺酸铝催化的二苯甲醇直接胺化，合成联芳胺衍生物。
General description
2-氯乙酰胺，又称为α-氯乙酰胺，是一种有机氯化合物，常用作前体合成酰胺和硫醇酰胺类化合物。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Repr. 2 - Skin Sens. 1
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 2
flash_point_f
338.0 °F
flash_point_c
170 °C
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Jun Zhang et al.
Journal of agricultural and food chemistry, 59(9), 4614-4621 (2011-03-23)
A butachlor-degrading strain, designated FLY-8, was isolated from rice field soil and was identified as Paracoccus sp. Strain FLY-8 could degrade and utilize six chloroacetamide herbicides as carbon sources for growth, and the degradation rates followed the order alachlor >
Cleonice Rocha et al.
Environmental pollution (Barking, Essex : 1987), 152(1), 239-244 (2007-07-17)
Solid-phase microextraction coupled with gas chromatography-mass spectrometry (SPME-GC-MS) was used to analyze two triazine (atrazine and simazine) and three chloroacetamide herbicides (acetochlor, alachlor, and metolachlor) in water samples from a midwest US agricultural drainage ditch for two growing seasons. The
Ezgi Odabasi et al.
EMBO reports, 20(6) (2019-04-27)
Centriolar satellites are ubiquitous in vertebrate cells. They have recently emerged as key regulators of centrosome/cilium biogenesis, and their mutations are linked to ciliopathies. However, their precise functions and mechanisms of action remain poorly understood. Here, we generated a kidney
Michelle L Hladik et al.
Environmental science & technology, 39(17), 6561-6574 (2005-09-30)
Although laboratory studies have revealed that many different neutral degradates of chloroacetamide herbicides can form during thermochemical, biological, and photochemical transformations, relatively few have been sought in the environment, despite their likely generation in appreciable amounts, relative persistence, and known
Yasmine Souissi et al.
Journal of chromatography. A, 1310, 98-112 (2013-09-10)
The photooxidation of acetochlor (a pesticide belonging to the acetamides group) using a polychromatic UV irradiation in ultrapure water was studied. This study reports the efficiency of mass spectrometry for the characterization of photodegradation products of acetochlor. Decompositions of protonated
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