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Merck
CN

B9807

Sigma-Aldrich

1,1,2,2-四苯基-1,2-乙二醇

99%

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别名:
苯频哪醇
线性分子式:
(C6H5)2C(OH)C(C6H5)2OH
CAS号:
分子量:
366.45
Beilstein:
2061947
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

99%

形式

crystals

mp

171-173 °C (lit.)

SMILES字符串

OC(c1ccccc1)(c2ccccc2)C(O)(c3ccccc3)c4ccccc4

InChI

1S/C26H22O2/c27-25(21-13-5-1-6-14-21,22-15-7-2-8-16-22)26(28,23-17-9-3-10-18-23)24-19-11-4-12-20-24/h1-20,27-28H

InChI key

MFEWNFVBWPABCX-UHFFFAOYSA-N

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应用

  • 1,1,2,2-Tetraphenyl-1,2-ethanediol (TPED) is used as an active component of the initiation system in free radical polymerization.
  • It is used as a precursor to prepare 1-hydroxy-2-(p-tolylaminocarbonyloxy)-1,1,2,2-tetraphenylethane (HTTPE), a thermal iniferter for radical polymerization.
  • TPED can also be used as a protecting group for the boronic acids by converting them to stable boronic esters.

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


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1, 1, 2, 2-Tetraphenyl-1, 2-ethanediol: A new protecting group for the synthesis of cyclopropylboronic esters.
Pietruszka J and Witt A
Synlett, 2003(01), 0091-0094 (2003)
Synthesis of well?defined polystyrene by radical polymerization using 1, 1, 2, 2?tetraphenyl?1, 2?ethanediol/feCl3/PPh3 initiation system.
Chen X P and Qiu K Y
Journal of Applied Polymer Science, 77(7), 1607-1613 (2000)
A novel thermal iniferter for radical polymerization.
Chen X P, et al.
European Polymer Journal, 36(8), 1547-1554 (2000)
Synthesis of well-defined poly (methyl methacrylate) by radical polymerization with a new initiation system TPED/FeCl3/PPh3.
Chen X P and Qiu K Y
Macromolecules, 32(26), 8711-8715 (1999)

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