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方案
98%
表单
powder
沸点
110-115 °C/15 mmHg (lit.)
mp
62-70 °C (lit.)
SMILES字符串
CC(C)(C)C1CCC(O)CC1
InChI
1S/C10H20O/c1-10(2,3)8-4-6-9(11)7-5-8/h8-9,11H,4-7H2,1-3H3
InChI key
CCOQPGVQAWPUPE-UHFFFAOYSA-N
应用
4-叔-正丁基环己醇（顺式和反式混合物）可作为反应物，用于合成三（4,4′-二-叔-丁基-2,2′- 联吡啶）（反式-4-叔-丁基环己醇）十-μ-氧化-七氧化七氧化钒簇合物，通过与[V8O20(C18H24N2)4]反应。还可以沸石BEA作为立体选择性催化剂，用作竞争对手Oppenauer氧化实验的反应物。仅将顺式-异构体选择性转化为对应的酮，而顺式-异构体保持不变。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2
储存分类代码
11 - Combustible Solids
WGK
WGK 1
闪点(°F)
221.0 °F - closed cup
闪点(°C)
105 °C - closed cup
个人防护装备
Eyeshields, Gloves, type N95 (US)
Tris (4, 4?-di-tert-butyl-2, 2?-bipyridine)(trans-4-tert-butylcyclohexanolato) deca- ? -oxido-heptaoxidoheptavanadium acetonitrile monosolvate including another unknown solvent molecule
Kodama S, et al.
IUCrData, 5(4), x200449-x200449 (2020)
Stereoselective Meerwein-Ponndorf-Verley and Oppenauer reactions catalysed by zeolite BEA
Creyghton EJ, et al.
J. Mol. Catal. A: Chem., 115(3), 457-472 (1997)
Mireia Oromí-Farrús et al.
Journal of analytical methods in chemistry, 2012, 452949-452949 (2012-06-01)
The use of iodine as a catalyst and either acetic or trifluoroacetic acid as a derivatizing reagent for determining the enantiomeric composition of acyclic and cyclic aliphatic chiral alcohols was investigated. Optimal conditions were selected according to the molar ratio
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