B80100
2-溴吡啶
99%
别名:
α-溴氮杂苯, β-溴吡啶, 2-溴吡, 邻溴吡啶
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关于此项目
经验公式（希尔记法）:
C5H4BrN
化学文摘社编号:
分子量:
158.00
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-641-6
Beilstein/REAXYS Number:
105789
MDL number:
产品名称
2-溴吡啶, 99%
InChI key
IMRWILPUOVGIMU-UHFFFAOYSA-N
InChI
1S/C5H4BrN/c6-5-3-1-2-4-7-5/h1-4H
SMILES string
Brc1ccccn1
assay
99%
form
liquid
refractive index
n20/D 1.572 (lit.)
bp
192-194 °C (lit.)
density
1.657 g/mL at 25 °C (lit.)
Quality Level
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Application
2-溴吡啶可用作：
- 通过各种交叉偶联反应形成C−N键的合成砌块。
- 通过钯催化与卤代芳烃进行Negishi交叉偶联反应的反应剂。
- 在存在铜的条件下，用作催化合成2′-吡啶二氟乙酸乙酯的反应剂。
General description
2-溴吡啶是一种有机化合物，广泛用作 有机合成中的合成砌块。它还用作 合成吡啶衍生物的中间体。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
195.1 °F - closed cup
flash_point_c
90.6 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Synthesis of solid 2-pyridylzinc reagents and their application in Negishi reactions.
Colombe JR, et al.
Organic Letters, 15(22), 5754-5757 (2013)
A Versatile and Efficient Ligand for Copper-Catalyzed Formation of C-N, C-O, and P-C Bonds: Pyrrolidine-2-Phosphonic Acid Phenyl Monoester.
Rao H, et al.
Chemistry?A European Journal , 12(13), 3636-3646 (2006)
Nicolas Großmann et al.
Dalton transactions (Cambridge, England : 2003), 45(45), 18365-18376 (2016-11-05)
Recently, research has revealed that molecules can be used to steer the local spin properties of ferromagnetic surfaces. One possibility to manipulate ferromagnetic-metal-molecule interfaces in a controlled way is to synthesize specific, non-magnetic molecules to obtain a desired interaction with
Amino acid promoted CuI-catalyzed C-N bond formation between aryl halides and amines or N-containing heterocycles.
Zhang H, et al.
The Journal of Organic Chemistry, 70(13), 5164-5173 (2005)
Synthesis of 2, 2?-Bipyridines: Versatile Building Blocks for Sexy Architectures and Functional Nanomaterials
GR Newkome, et al.
European Journal of Organic Chemistry, 2004, 235-254 (2004)
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