质量水平
检测方案
98%
形式
liquid
包含
copper as stabilizer
折射率
n20/D 1.4538 (lit.)
bp
58-63 °C (lit.)
mp
−116 °C (lit.)
密度
1.413 g/mL at 25 °C (lit.)
SMILES字符串
C\C=C\Br
InChI
1S/C3H5Br/c1-2-3-4/h2-3H,1H3/b3-2+
InChI key
NNQDMQVWOWCVEM-NSCUHMNNSA-N
应用
1-溴-1-丙烯经n正丁基锂处理后原位生成丙炔基锂阴离子，随后发生亲核加成反应。它的一些其他应用包括：
- 合成有机试剂，例如丁炔酸甲酯和1-碘丙炔。
- （+）-aphanamol I和Skyllamycins AC全合成中间体的制备。
- 烯丙基化吡唑，芳基炔基硫醚和烯丙酰胺的合成。
警示用语：
Danger
危险分类
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
Gold (I)?Catalyzed Intermolecular [2+ 2] Cycloadditions between Allenamides and Alkenes.
Faustino H, et al.
Advanced Synthesis & Catalysis, 354(9), 1658-1664 (2012)
Synthesis of 1?Iodopropyne.
Bartko S G, et al.
Organic Syntheses, 93, 245-262 (2003)
Asymmetric total synthesis of (+)-aphanamol I based on the transition metal catalyzed [5+ 2] cycloaddition of allenes and vinylcyclopropanes.
Wender P A and Zhang L
Organic Letters, 2(15), 2323-2326 (2000)
Regioconvergent and Enantioselective Rhodium?Catalyzed Hydroamination of Internal and Terminal Alkynes: A Highly Flexible Access to Chiral Pyrazoles.
Haydl A M, et al.
Chemistry?A European Journal , 22(19), 6547-6551 (2016)
Total Synthesis of Skyllamycins A?C.
Total Synthesis of Natural Products, 119-150 (2018)
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