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质量水平
方案
97%
表单
liquid
折射率
n20/D 1.6570 (lit.)
沸点
133-134 °C/10 mmHg (lit.)
mp
−2-−1 °C (lit.)
密度
1.48 g/mL at 20 °C (lit.)
SMILES字符串
Brc1cccc2ccccc12
InChI
1S/C10H7Br/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H
InChI key
DLKQHBOKULLWDQ-UHFFFAOYSA-N
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一般描述
1-溴萘可用作交叉偶联反应合成联芳基化合物的中间体。
应用
1-溴萘一种溴代芳烃，可用于：
- 与芳基三氟硼酸的钯催化Suzuki–Miyaura偶联反应，无需相转移催化剂或膦配体。
- 通过Suzuki-Heck型偶联，与o-溴苯基硼酸和寡环溴芳烃反应，制备Indeno环并多环芳烃。
- 与PhMgBr的Ni催化Kumada–Tamao–Corriu 交叉偶联反应。
- 通过与芳基硼酸的钯催化Suzuki-Miyaura交叉偶联反应制备芳基萘。
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
230.0 °F - closed cup
闪点(°C)
110 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Exploring the selectivity of the Suzuki-Miyaura cross-coupling reaction in the synthesis of arylnaphthalenes
Lima CFRAC, et al.
Tetrahedron, 67(4), 689-697 (2011)
High efficiency of cavity-based triaryl-phosphines in nickel-catalysed Kumada-Tamao-Corriu cross-coupling
Monnereau L, et al.
Chemical Communications (Cambridge, England), 47(23), 6626-6628 (2011)
Microwave-accelerated Suzuki-Miyaura coupling reactions using potassium aryltrifluoroborates
Harker RL and Crouch RD
Synthesis, 2007(01), 25-27 (2007)
A New Suzuki- Heck-Type Coupling Cascade: Indeno [1, 2, 3]-Annelation of Polycyclic Aromatic Hydrocarbons
Wegner HA, et al.
The Journal of Organic Chemistry, 68(3), 883-887 (2003)
Xinzhen Du et al.
Journal of colloid and interface science, 274(2), 645-651 (2004-05-18)
The binding of polyethylene glycol (10) n-octylphenyl ether (OPE) and polyethylene glycol (10) tert-octylphenyl ether (Triton X-100, TX) to beta-cyclodextrin (beta-CD) and heptakis(2,3- beta-dimethyl)- beta-CD (DM- beta-CD) was described in detail by surface tension, steady-state fluorescence of OPE and TX
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