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质量水平
方案
98%
表单
liquid
折射率
n20/D 1.552 (lit.)
沸点
225 °C (lit.)
mp
2 °C (lit.)
密度
1.301 g/mL at 25 °C (lit.)
SMILES字符串
Cc1cc(C)c(Br)c(C)c1
InChI
1S/C9H11Br/c1-6-4-7(2)9(10)8(3)5-6/h4-5H,1-3H3
InChI key
RRTLQRYOJOSPEA-UHFFFAOYSA-N
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一般描述
2-三甲基溴苯可以用作碳-碳键的形成和裂解反应中的反应物。
Nitrile-group transfer from solvents to aryl halides. novel carbon- carbon bond formation and cleavage mediated by palladium and zinc species
Luo FH, et al.
Organometallics, 17, 1025-1030 (1998)
Karlee L Bamford et al.
Dalton transactions (Cambridge, England : 2003), 49(48), 17571-17577 (2020-11-25)
The synthesis and isolation of the first stable C-B-N-substituted borinium [MesBNiPr2][B(C6F5)4] (2) is described. Compound 2 was shown to react with isothiocyanate and carbodiimides, effecting B-C insertion to afford nitrilium (4) and borenium amidinate salts, respectively. The borinium cation [MesBNiPr2]+
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