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线性分子式:
BrCH2CH2NH2 · HBr
化学文摘社编号:
分子量:
204.89
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
219-924-2
Beilstein/REAXYS Number:
3607605
MDL number:
Assay:
99%
Form:
crystals
InChI key
WJAXXWSZNSFVNG-UHFFFAOYSA-N
InChI
1S/C2H6BrN.BrH/c3-1-2-4;/h1-2,4H2;1H
SMILES string
Br.NCCBr
assay
99%
form
crystals
Quality Level
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General description
2-溴乙胺氢溴酸盐,又称2-氨基乙基溴氢溴酸盐,是简单、常用的无害物质。通过NaBr消除可提供钛酸盐纳米管用–NH2。另外,它可溶于水中,取代有害的有机溶剂作为优质改性试剂。
Application
2-溴乙胺氢溴酸盐可作为反应物用于合成:
- 噻唑类和噻嗪类,通过硫代酰胺/卤代胺串联 S-烷基化-环脱氨基作用合成。
- 有光学活性的叔磷,通过氢氧化铯催化仲膦的 P-烷基化反应
- 仲胺,通过CsOH促进伯胺、二胺和多胺的化学选择性单-N-烷基化反应。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3
存储类别
11 - Combustible Solids
flash_point_f
142.9 °F - Pensky-Martens closed cup
flash_point_c
61.6 °C - Pensky-Martens closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Synthesis, 1040-1040 (2006)
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S Garrod et al.
Magnetic resonance in medicine, 45(5), 781-790 (2001-04-27)
The metabolic consequences of xenobiotic-induced toxicity were investigated using high-resolution magic angle spinning (MAS) NMR spectroscopy of intact tissue. Renal papillary necrosis (RPN) was induced in Sprague-Dawley rats (n = 12) via a single i.p. dose of 250 mg/kg 2-bromoethanamine
Zhenfeng An et al.
Journal of experimental botany, 59(4), 815-825 (2008-02-15)
H(2)O(2) is an essential signal in absicic acid (ABA)-induced stomatal closure. It can be synthesized by several enzymes in plants. In this study, the roles of copper amine oxidase (CuAO) in H(2)O(2) production and stomatal closure were investigated. Exogenous ABA
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