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质量水平
方案
≥99.0%
表单
liquid
折射率
n20/D 1.564 (lit.)
沸点
223 °C (lit.)
mp
9-10 °C (lit.)
密度
1.494 g/mL at 25 °C (lit.)
SMILES字符串
COc1ccc(Br)cc1
InChI
1S/C7H7BrO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3
InChI key
QJPJQTDYNZXKQF-UHFFFAOYSA-N
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一般描述
4-溴苯甲醚一种实用的溴化试剂。它是在HOBr与苯甲醚之间的反应中形成的反应产物。已有研究报道了由钳形钯复合物催化的4-溴苯甲醚与苯硼酸的Suzuki偶联反应。据报道，在室温离子液体中，4-溴苯甲醚与丙烯酸乙酯发生Heck反应，形成4-甲氧基肉桂酸。
应用
4-溴苯甲醚被用于合成芳基1,3-二酮。
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Oral - Skin Irrit. 2
储存分类代码
10 - Combustible liquids
WGK
WGK 2
闪点(°F)
201.2 °F
闪点(°C)
94 °C
个人防护装备
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
法规信息
危险化学品
Amy E Bryant et al.
PloS one, 12(2), e0172486-e0172486 (2017-03-01)
Acute muscle injuries are exceedingly common and non-steroidal anti-inflammatory drugs (NSAIDs) are widely consumed to reduce the associated inflammation, swelling and pain that peak 1-2 days post-injury. While prophylactic use or early administration of NSAIDs has been shown to delay
Palladium bis (phosphinite)'PCP'-pincer complexes and their application as catalysts in the Suzuki reaction.
Bedford RB, et al.
New. J. Chem., 24(10), 745-747 (2000)
Dennis U Nielsen et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(52), 17926-17938 (2013-11-23)
Reaction conditions for the three-component synthesis of aryl 1,3-diketones are reported applying the palladium-catalyzed carbonylative α-arylation of ketones with aryl bromides. The optimal conditions were found by using a catalytic system derived from [Pd(dba)2] (dba=dibenzylideneacetone) as the palladium source and
Yasuyuki Nakamura et al.
Applied and environmental microbiology, 84(15) (2018-05-29)
The methylotrophic yeast Pichia pastoris is widely used to produce recombinant proteins, taking advantage of this species' high-density cell growth and strong ability to secrete proteins. Circular plasmids containing the P. pastoris-specific autonomously replicating sequence (PARS1) permit transformation of P.
John D Sivey et al.
Environmental science & technology, 49(8), 4937-4945 (2015-03-25)
When bromide-containing waters are chlorinated, conventional wisdom typically assumes HOBr is the only active brominating agent. Several additional and often-overlooked brominating agents (including BrCl, Br2, BrOCl, Br2O) can form in chlorinated waters, albeit at generally lower concentrations than HOBr. The
商品
Heck反应是烯烃与芳基或乙烯基卤化物（或三氟甲磺酸酯）之间的钯催化交叉偶联反应，用于生成取代的烯烃。
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