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质量水平
方案
≥99.0%
表单
liquid
折射率
n20/D 1.564 (lit.)
沸点
223 °C (lit.)
mp
9-10 °C (lit.)
密度
1.494 g/mL at 25 °C (lit.)
SMILES字符串
COc1ccc(Br)cc1
InChI
1S/C7H7BrO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3
InChI key
QJPJQTDYNZXKQF-UHFFFAOYSA-N
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一般描述
4-溴苯甲醚一种实用的溴化试剂。它是在HOBr与苯甲醚之间的反应中形成的反应产物。已有研究报道了由钳形钯复合物催化的4-溴苯甲醚与苯硼酸的Suzuki偶联反应。据报道，在室温离子液体中，4-溴苯甲醚与丙烯酸乙酯发生Heck反应，形成4-甲氧基肉桂酸。
应用
4-溴苯甲醚被用于合成芳基1,3-二酮。
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Oral - Skin Irrit. 2
储存分类代码
10 - Combustible liquids
WGK
WGK 2
闪点(°F)
201.2 °F
闪点(°C)
94 °C
个人防护装备
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
法规信息
危险化学品
Palladium bis (phosphinite)'PCP'-pincer complexes and their application as catalysts in the Suzuki reaction.
Bedford RB, et al.
New. J. Chem., 24(10), 745-747 (2000)
Dennis U Nielsen et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(52), 17926-17938 (2013-11-23)
Reaction conditions for the three-component synthesis of aryl 1,3-diketones are reported applying the palladium-catalyzed carbonylative α-arylation of ketones with aryl bromides. The optimal conditions were found by using a catalytic system derived from [Pd(dba)2] (dba=dibenzylideneacetone) as the palladium source and
Amy E Bryant et al.
PloS one, 12(2), e0172486-e0172486 (2017-03-01)
Acute muscle injuries are exceedingly common and non-steroidal anti-inflammatory drugs (NSAIDs) are widely consumed to reduce the associated inflammation, swelling and pain that peak 1-2 days post-injury. While prophylactic use or early administration of NSAIDs has been shown to delay
John D Sivey et al.
Environmental science & technology, 49(8), 4937-4945 (2015-03-25)
When bromide-containing waters are chlorinated, conventional wisdom typically assumes HOBr is the only active brominating agent. Several additional and often-overlooked brominating agents (including BrCl, Br2, BrOCl, Br2O) can form in chlorinated waters, albeit at generally lower concentrations than HOBr. The
Besma Harzallah et al.
Environmental science and pollution research international, 24(16), 14376-14386 (2017-04-23)
Phenol hydroxylases (PHs) play a primary role in the bacterial degradation of phenol and alkylphenols. They are divided into two main classes, single-component and multi-component PHs, having distinctive catalytic subunits designated as PheA1 and LmPH, respectively. The diversity of these
商品
Heck反应是烯烃与芳基或乙烯基卤化物（或三氟甲磺酸酯）之间的钯催化交叉偶联反应，用于生成取代的烯烃。
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