B56501
4-溴苯甲醚
≥99.0%
别名:
1-溴-4-甲氧基苯
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线性分子式:
BrC6H4OCH3
化学文摘社编号:
分子量:
187.03
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-252-1
Beilstein/REAXYS Number:
1237590
MDL number:
Assay:
≥99.0%
Form:
liquid
InChI key
QJPJQTDYNZXKQF-UHFFFAOYSA-N
InChI
1S/C7H7BrO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3
SMILES string
COc1ccc(Br)cc1
assay
≥99.0%
form
liquid
Quality Level
bp
223 °C (lit.)
mp
9-10 °C (lit.)
density
1.494 g/mL at 25 °C (lit.)
General description
4-溴苯甲醚一种实用的溴化试剂。它是在HOBr与苯甲醚之间的反应中形成的反应产物。已有研究报道了由钳形钯复合物催化的4-溴苯甲醚与苯硼酸的Suzuki偶联反应。据报道，在室温离子液体中，4-溴苯甲醚与丙烯酸乙酯发生Heck反应，形成4-甲氧基肉桂酸。
Application
4-溴苯甲醚被用于合成芳基1,3-二酮。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Skin Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 2
flash_point_f
201.2 °F
flash_point_c
94 °C
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
法规信息
危险化学品
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Amy E Bryant et al.
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Palladium bis (phosphinite)'PCP'-pincer complexes and their application as catalysts in the Suzuki reaction.
Bedford RB, et al.
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