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Merck
CN

B52808

Sigma-Aldrich

1,2-二(4-吡啶基)乙烯

97%

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别名:
1,2-双(4-吡啶)乙烯, 4,4′-乙烯基二吡啶
经验公式(希尔记法):
C12H10N2
CAS号:
分子量:
182.22
Beilstein:
3865
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

97%

形式

crystals

mp

148-152 °C (lit.)

SMILES字符串

c1cc(ccn1)\C=C\c2ccncc2

InChI

1S/C12H10N2/c1(11-3-7-13-8-4-11)2-12-5-9-14-10-6-12/h1-10H/b2-1+

InChI key

MGFJDEHFNMWYBD-OWOJBTEDSA-N

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应用

1,2-双(4-吡啶)乙烯广泛用作各种金属有机骨架配合物(MOF)和配位聚合物(CP)合成方面的配体/接头。它用于合成:
  • 扩缩镉基层柱配位聚合物,表现出选择性客体吸附。
  • 双核锌配合物,显示光控荧光。
  • 铂基三维四方棱镜,通过多组分配位驱动自组装。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


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Expanding and Shrinking Porous Modulation Based on Pillared-Layer Coordination Polymers Showing Selective Guest Adsorption.
Maji TK, et al.
Angewandte Chemie (International Edition in English), 43(25), 3269-3272 (2004)
Isoreticular Homochiral Porous Metal- Organic Structures with Tunable Pore Sizes.
Dybtsev DN, et al.
Inorganic Chemistry, 46(17), 6843-6845 (2007)
Zhiwei Chen et al.
Dalton transactions (Cambridge, England : 2003), 47(17), 6240-6249 (2018-04-25)
Three new luminescent transition coordination polymers, namely, {[Cd(L)(4,4-bpy)]·DMF·H2O}n (1), {[Cd2(L)2(bpe)2]·3DMF·2.5H2O}n (2), and {[Cd(L)(bibp)]·2DMF}n (3), (H2L = 4,4'-[benzene-1,3-diylbis(methanediylsulfanediyl)]dibenzoic acid, 4,4-bpy = 4,4-bipyridine, bpe = 1,2-bis(4-pyridyl)ethylene, and bibp = 4,4'-bis(benzoimidazo-1-ly)biphenyl), were solvothermally synthesized using Cd2+ ions and S-containing dicarboxylate acid in the
Jun-Hui Zhang et al.
Electrophoresis, 38(19), 2513-2520 (2017-07-06)
Natural amino acids are well known to form coordination polymers with transition metal ions. In this study, six homochiral metal-organic frameworks constructed from Zn
Ekaterina Babich et al.
Nanomaterials (Basel, Switzerland), 10(9) (2020-09-20)
The irradiation of silver-to-sodium ion-exchanged glass with 1.06-μm nanosecond laser pulses of mJ-range energy results in the formation of silver nanoparticles under the glass surface. Following chemical removal of ~25-nm glass layer reveals a pattern of nanoparticles capable of surface

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