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Merck
CN
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文件

安全信息

B33803

Sigma-Aldrich

双环[2.2.1]庚-2,5-二烯

98%

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别名:
2,5-降冰片二烯, NBD
经验公式（希尔记法）:
C7H8
CAS号:
121-46-0
分子量:
92.14
Beilstein:
506224
MDL编号:
MFCD00082301
UNSPSC代码:
12352300
PubChem化学物质编号:
24891712
NACRES:
NA.23

质量水平

200

检测方案

98%

形式

liquid

包含

0.05-0.25% BHT as inhibitor

折射率

n20/D 1.470 (lit.)

bp

89 °C (lit.)

密度

0.906 g/mL at 25 °C (lit.)

SMILES字符串

C1[C@H]2C=C[C@@H]1C=C2

InChI

1S/C7H8/c1-2-7-4-3-6(1)5-7/h1-4,6-7H,5H2/t6-,7+

InChI key

SJYNFBVQFBRSIB-KNVOCYPGSA-N

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相关类别

应用

前列腺素合成中间体。

特点和优势

前列腺素合成中间体。

象形图

Flame
GHS02

警示用语：

Danger

危险声明

H225,H412

危险分类

Aquatic Chronic 3 - Flam. Liq. 2

WGK

WGK 2

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

分析证书(COA)

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Praew Thansandote et al.
The Journal of organic chemistry, 74(4), 1673-1678 (2009-01-16)
A general procedure for the palladium-catalyzed annulation of substituted haloanilines with norbornadiene gives functionalized indolines in 51-98% yield. These indolines can be rapidly converted to benzenoid-substituted indoles and tricyclic indolines. Extension to the use of substituted halobenzamides gives functionalized isoquinolinones
M Victoria Jiménez et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(29), 8115-8128 (2011-06-03)
The treatment of [{Rh(μ-SH){P(OPh)(3)}(2)}(2)] with [{M(μ-Cl)(diolef)}(2)] (diolef=diolefin) in the presence of NEt(3) affords the hydrido-sulfido clusters [Rh(3)(μ-H)(μ(3)-S)(2)(diolef){P(OPh)(3)}(4)] (diolef=1,5-cyclooctadiene (cod) for 1, 2,5-norbornadiene (nbd) for 2, and tetrafluorobenzo[5,6]bicyclo[2.2.2]octa-2,5,7-triene (tfb) for 3) and [Rh(2)Ir(μ-H)(μ(3)-S)(2)(cod){P(OPh)(3)}(4)] (4). Cluster 1 can be also obtained by
Paulo M Nunes et al.
The journal of physical chemistry. A, 113(23), 6524-6530 (2009-05-20)
The energetics of tert-butoxyl radical addition reaction to norbornadiene was investigated by time-resolved photoacoustic calorimetry (TR-PAC). The result, together with the C-O bond dissociation enthalpy (BDE) in the addition product, allowed us to calculate the pi-bond dissociation enthalpy in norbornadiene.
S Philosoph-Hadas et al.
Plant physiology, 110(1), 301-310 (1996-01-01)
The possible involvement of Ca2+ as a second messenger in snapdragon (Antirrhinum majus L.) shoot gravitropism, as well as the role of ethylene in this bending response, were analyzed in terms of stem curvature and gravity-induced asymmetric ethylene production rates
Bianka Steffens et al.
Planta, 223(3), 604-612 (2005-09-15)
Growth of adventitious roots is induced in deepwater rice (Oryza sativa L.) when plants become submerged. Ethylene which accumulates in flooded plant parts is responsible for root growth induction. Gibberellin (GA) is ineffective on its own but acts in a
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