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安全信息

B32602

Sigma-Aldrich

苄基三甲基氢氧化铵 溶液

40 wt. % in methanol

别名:

N,N,N-Trimethyl-N-benzylammonium hydroxide, N,N,N-trimethyl-1-phenylmethanaminium hydroxide, N,N,N-trimethylbenzenemethanaminium hydroxide, Triton B

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About This Item

线性分子式:
C6H5CH2N(OH)(CH3)3
CAS号:
100-85-6
分子量:
167.25
Beilstein:
3917256
MDL编号:
MFCD00008281
UNSPSC代码:
12352005
PubChem化学物质编号:
24891693
NACRES:
NA.22

表单

liquid

质量水平

200

浓度

40 wt. % in methanol

密度

0.92 g/mL at 25 °C

SMILES字符串

[OH-].C[N+](C)(C)Cc1ccccc1

InChI

1S/C10H16N.H2O/c1-11(2,3)9-10-7-5-4-6-8-10;/h4-8H,9H2,1-3H3;1H2/q+1;/p-1

InChI key

NDKBVBUGCNGSJJ-UHFFFAOYSA-M

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相关类别

一般描述

苄基三甲基氢氧化铵溶液是一种季铵盐化合物，常用作有机合成中的碱。也用作几种聚合反应的碱性催化剂。

应用

苄基三甲基氢氧化铵溶液可用于：     
  • 作为nitroaldol缩合反应的催化剂
  • 作为结构导向剂，用于水热法合成富二氧化硅的铝硅酸盐沸石（菱沸石型）
  • 作为离子液体前体制备ZnO纳米结构颗粒

警示用语：

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 1

靶器官

Eyes,Central nervous system

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

51.8 °F - closed cup

闪点(°C)

11 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCT8608
MKCQ7163
MKCP1402
MKCL3441
MKCJ0581

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L Sangeetha Vedula et al.
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Journal of chromatography. A, 1218(15), 1966-1973 (2010-10-05)
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Purushothaman Gopinath et al.
The Journal of organic chemistry, 74(16), 6291-6294 (2009-07-22)
An efficient protocol is reported for the synthesis of thioesters from carboxylic acids with use of acyloxy phosphonium salts as intermediates and benzyltriethylammonium tetrathiomolybdate as the sulfur transfer reagent.
Weisheng Lin et al.
Analytica chimica acta, 583(1), 98-102 (2007-03-28)
The importance of benzyltriethyl ammonium chloride (BTEAC) in industrial applications has stimulated the development of a number of methods for its determination. In this paper, a high performance capillary electrophoresis (CE) method, coupled with an extraction technique for determining BTEAC
Li Zaijun et al.
Journal of AOAC International, 90(4), 1191-1196 (2007-09-01)
The ionic liquid 1-butyl-3-trimethylsilylimidazolium hexafluorophosphate, abbreviated as [C4tmsim][PF6], was developed as a novel medium for liquid-liquid extraction of lead(II) in water, in which dithizone was used as a metal chelator to form a neutral lead-dithizone complex. Under optimal conditions, the
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