等级
reagent grade
质量水平
蒸汽密度
5.8 (vs air)
检测方案
98%
形式
liquid
杂质
≤0.5% p-bromotoluene
折射率
n20/D 1.575 (lit.)
bp
198-199 °C (lit.)
mp
−3-−1 °C (lit.)
密度
1.438 g/mL at 25 °C (lit.)
SMILES字符串
BrCc1ccccc1
InChI
1S/C7H7Br/c8-6-7-4-2-1-3-5-7/h1-5H,6H2
InChI key
AGEZXYOZHKGVCM-UHFFFAOYSA-N
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一般描述
苄基溴是一种芳香卤化物，主要用作保护剂，通过 O-苄基化反应保护醇的羟基。
应用
苄基溴已被用作通过原子转移自由基聚合反应合成聚（苯乙烯-b-甲基丙烯酸甲酯）共聚物的引发剂。它可以与1,2-二甲基咪唑发生Menschutkin反应，形成3-苄基-1,2-二甲基咪唑鎓溴化物。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 2
闪点(°F)
186.8 °F
闪点(°C)
86 °C
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Vanderlisa Rita Meleti et al.
Acta tropica, 202, 105248-105248 (2019-11-05)
This paper reports the synthesis of (±)-licarin A 1, a dihydrobenzofuran neolignan, resultant of an oxidative coupling reaction of isoeugenol and horseradish peroxidase (HRP) enzyme. Following, three semi-synthetic derivatives from this compound were obtained: benzylated (±)-licarin A 2, methylated (±)-licarin
Rate constants for reaction of 1, 2-dimethylimidazole with benzyl bromide in ionic liquids and organic solvents.
Skrzypczak A and Neta P.
International Journal of Chemical Kinetics, 36(4), 253-258 (2004)
Hon Man Yau et al.
Molecules (Basel, Switzerland), 14(7), 2521-2534 (2009-07-28)
While there has been much effort in recent years to characterise ionic liquids in terms of parameters that are well described for molecular solvents, using these to explain reaction outcomes remains problematic. Herein we propose that many reaction outcomes in
Virender Kumar et al.
Theranostics, 8(15), 4033-4049 (2018-08-22)
Rationale: Successful treatment of pancreatic cancer remains a challenge due to desmoplasia and prevalence of KRAS mutation. While hedgehog (Hh) ligand levels are upregulated in pancreatic cancer cells and contribute to desmoplasia, there is significant downregulation of tumor suppressor let-7b
A novel acid-catalyzed O-benzylating reagent with the smallest unit of imidate structure.
Yamada K
Organic Letters, 14(19), 5026-5029 (2012)
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