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Merck
CN
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文件

安全信息

ALD00633

Sigma-Aldrich

Methyl (+)-PI Reagent

≥95%

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别名:
1,3,2-Benzoxathiaphosphole, hexahydro-2,7a-dimethyl-5-(1-methylethenyl)-, 2-sulfide, (2R,3aR,5S,7aR)
经验公式（希尔记法）:
C11H19OPS2
CAS号:
2408772-80-3
分子量:
262.37
NACRES:
NA.06

质量水平

100

检测方案

≥95%

形式

powder

储存温度

2-8°C

SMILES字符串

C[C@]1(O[P@](S2)(C)=S)[C@@]2([H])C[C@@H](C(C)=C)CC1

应用

Methyl (+)-PI Reagent is a methyl substituted analog of the air and moisture-tolerant (+-)-PI reagent developed in the Baran lab for stereospecific synthesis of chiral phosphines and methylphosphonate nucleotides.

Learn more about PI and PSI reagents

其他说明

Enantiodivergent formation of C-P bonds: synthesis of P-chiral phosphines and methyl-phosphonate oligonucleotides

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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Dongmin Xu et al.
Journal of the American Chemical Society, 142(12), 5785-5792 (2020-02-29)
Phosphorus Incorporation (PI, abbreviated Π) reagents for the modular, scalable, and stereospecific synthesis of chiral phosphines and methylphosphonate nucleotides are reported. Synthesized from trans-limonene oxide, this reagent class displays an unexpected reactivity profile and enables access to chemical space distinct

商品

PI and PSI – Chiral phosphorus incorporation harnessing the potential of P(V)

PI and PSI reagents are a platform of phosphate-based reagents for phosphorylation and phosphothiolation of nucleotides and peptides developed by the Baran lab.

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