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Merck
CN
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安全信息

ALD00625

Sigma-Aldrich

PSIO

别名:

(2S,3aS,6R,7aS)-3a-Methyl-2-((4-bromophenyl)thio)-6-(prop-2-yl)hexahydrobenzo[d][1,3,2]oxathiaphosphole 2-oxide

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About This Item

经验公式（希尔记法）:
C16H22BrO2PS2
CAS号:
2702251-89-4
分子量:
421.35
UNSPSC代码:
12141909
NACRES:
NA.22

储存温度

2-8°C

质量水平

100

SMILES字符串

CC(C)[C@@H]1CC[C@@]2(C)[C@@H](O[P@](S2)(SC3=CC=C(Br)C=C3)=O)C1

应用

PSIO is a P(V) reagent developed by the Baran Lab as a part of the Ψ platform, used in the direct phosphorylation of alcohols. This reagent is scalable and easy to use under mild conditions, and is functional for a broad substrate scope, including many alcohols that are challenging to otherwise activate.

Learn more about PI and PSI reagents

其他说明

Mild and Chemoselective Phosphorylation of Alcohols Using a PSI-Reagent

Unlocking P(V):Reagents for chiral phosphorothioate synthesis

WGK

WGK 3

法规信息

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PI and PSI – Chiral phosphorus incorporation harnessing the potential of P(V)

PI and PSI reagents are a platform of phosphate-based reagents for phosphorylation and phosphothiolation of nucleotides and peptides developed by the Baran lab.

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