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方案
≥95%
表单
powder
反应适用性
reaction type: C-C Bond Formation
储存温度
−20°C
SMILES字符串
N([C@H](CN(C)C)Cc1ccccc1)C(=O)C
InChI
1S/C13H20N2O/c1-11(16)14-13(10-15(2)3)9-12-7-5-4-6-8-12/h4-8,13H,9-10H2,1-3H3,(H,14,16)/t13-/m0/s1
InChI key
PXPSPBKAWKBCMJ-ZDUSSCGKSA-N
应用
(S)-N-(1-(Dimethylamino)-3-phenylpropan-2-yl)acetamide is an MPAAM ligand developed in the Yu Group for the Pd-catalyzed enantioselective C(sp3)-H arylation of fre cyclopropanecarboxylic and aminoisobutyric acids.
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
Peng-Xiang Shen et al.
Journal of the American Chemical Society, 140(21), 6545-6549 (2018-05-10)
A monoprotected aminoethyl amine chiral ligand based on an ethylenediamine backbone was developed to achieve Pd-catalyzed enantioselective C(sp3)-H arylation of cyclopropanecarboxylic and 2-aminoisobutyric acids without using exogenous directing groups. This new chiral catalyst affords new disconnection for preparing diverse chiral
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