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方案
≥95%
表单
powder
反应适用性
reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation
mp
156-159 °C
储存温度
−20°C
SMILES字符串
Clc1nc(nc(n1)c2c(cccc2)C#N)OC
InChI key
IGHRYADFCQIVJY-UHFFFAOYSA-N
应用
2-(4-Chloro-6-methoxy-1,3,5-triazin-2-yl)benzonitrile is a bifunctional C-H activation template developed in the Yu lab for the conversion of phenols to 1,3-disubstituted arenes. The template is used for a one-pot Pd-catalyzed meta-selective C-H olefination of phenols followed by a nickel-catalyzed ipso-C-O activation and arylation.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
Jiancong Xu et al.
Journal of the American Chemical Society, 141(5), 1903-1907 (2019-01-23)
The use of a template as a linchpin motif in directed remote C-H functionalization is a versatile yet relatively underexplored strategy. We have developed a template-directed approach to realizing one-pot sequential palladium-catalyzed meta-selective C-H olefination of phenols, and nickel-catalyzed ipso-C-O
相关内容
Yu program focuses on efficient C–H bond activation for drug synthesis, using simple starting materials.
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