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ALD00608

Ni(bpy)₃Br₂

Name: Ni(bpy)<SUB>3</SUB>Br<SUB>2</SUB>
Brand: ALDRICH

别名:

Trisbipyridylnickel dibromide

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About This Item

经验公式（希尔记法）:

C₃₀H₂₄Br₂N₆Ni

分子量:

687.05

UNSPSC代码:

12352300

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903000

[4,4′-双（1,1-二甲基乙基）-2,2′-联吡啶]二氯化镍（II）

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ALD00558

1-((3,5-Difluorophenyl)sulfonyl)bicyclo[1.1.0]butane

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913278

[1,2-Bis(diphenylphosphino)ethane]dibromonickel(II)

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406341

乙二醇二甲醚溴化镍

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696668

氯化镍(II)乙二醇二甲基醚络合物

Sigma-Aldrich

515477

4,4′-二叔丁基-2,2′-联吡啶

Sigma-Aldrich

930857

Ni(bpy)Cl₂

Sigma-Aldrich

T84603

三苯基氧膦

Sigma-Aldrich

T84409

三苯基瞵

Sigma-Aldrich

902993

(BPhen)Ni(OAc)₂.xH₂O

表单

powder or crystals

反应适用性

reagent type: catalyst
reaction type: Cross Couplings

应用

Ni(bpy)₃Br₂ is a Ni precatalyst shown by the Baran Lab to be an effective catalyst for the electrochemical amination (e-amination) of arly halides with amines.

Product can be used with our Synlectro electrochemistry platform (ESYNTH001)

警示用语：

Danger

危险声明

H317,H334,H341,H350i,H360D,H372,H410

预防措施声明

P202 - P260 - P273 - P280 - P302 + P352 - P308 + P313

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1B - Skin Sens. 1B - STOT RE 1 Inhalation

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

从最新的版本中选择一种：

分析证书(COA)

Lot/Batch Number

MKCN8694

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Electrochemically Driven, Ni-Catalyzed Aryl Amination: Scope, Mechanism, and Applications.

Yu Kawamata et al.

Journal of the American Chemical Society, 141(15), 6392-6402 (2019-03-25)

C-N cross-coupling is one of the most valuable and widespread transformations in organic synthesis. Largely dominated by Pd- and Cu-based catalytic systems, it has proven to be a staple transformation for those in both academia and industry. The current study

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