所有图片(3)
About This Item
经验公式（希尔记法）:
C8HCl4NO3
CAS号:
分子量:
300.91
MDL编号:
UNSPSC代码:
12352111
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
表单
powder
质量水平
反应适用性
reagent type: oxidant
SMILES字符串
O=C1N(O)C(C2=C(Cl)C(Cl)=C(Cl)C(Cl)=C21)=O
InChI
1S/C8HCl4NO3/c9-3-1-2(4(10)6(12)5(3)11)8(15)13(16)7(1)14/h16H
InChI key
UTRBHXSKVVPTLY-UHFFFAOYSA-N
一般描述
N-羟基四氯邻苯二甲酰亚胺（TCNHPI）是一种芳基-四卤代N-羟基邻苯二甲酰亚胺衍生物。与1,4-二氨基-2,3-二氯蒽醌（DADCAQ）组合可形成一种有效的催化系统，用于在无金属和有氧条件下利用分子氧实现芳烃的氧化反应。
应用
新试剂能够实现Baran团队开发的电化学烯丙基C-H氧化反应。该方法为当前基于有毒试剂或贵金属的方法提供了一种可扩展且可持续的替代方案。
警示用语：
Danger
危险声明
危险分类
Acute Tox. 3 Oral
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
从最新的版本中选择一种：
分析证书(COA)
Lot/Batch Number
Tian Qin et al.
Science (New York, N.Y.), 352(6287), 801-805 (2016-04-23)
Alkyl carboxylic acids are ubiquitous in all facets of chemical science, from natural products to polymers, and represent an ideal starting material with which to forge new connections. This study demonstrates how the same activating principles used for decades to
Jie Wang et al.
Angewandte Chemie (International ed. in English), 55(33), 9676-9679 (2016-07-07)
A transformation analogous in simplicity and functional group tolerance to the venerable Suzuki cross-coupling between alkyl-carboxylic acids and boronic acids is described. This Ni-catalyzed reaction relies upon the activation of alkyl carboxylic acids as their redox-active ester derivatives, specifically N-hydroxy-tetrachlorophthalimide
Efficient metal-free aerobic oxidation of aromatic hydrocarbons utilizing aryl-tetrahalogenated N-hydroxyphthalimides and 1,4-diamino-2,3-dichloroanthraquinone.
Zhang Q, et al.
Journal of Chemical Technology and Biotechnology, 83(10), 1364-1369 (2008)
Josep Cornella et al.
Journal of the American Chemical Society, 138(7), 2174-2177 (2016-02-03)
A new transformation is presented that enables chemists to couple simple alkyl carboxylic acids with aryl zinc reagents under Ni-catalysis. The success of this reaction hinges on the unique use of redox-active esters that allow one to employ such derivatives
商品
Phil Baran develops ALD00564 reagent as a safe, cost-effective alternative for allylic oxidations and cross-coupling reactions.
相关内容
Baran Group offers zinc-based reagents for versatile transformations in organic synthesis.
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系技术服务部门