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Merck
CN

ALD00170

Sigma-Aldrich

1,2-苯二磺酰氟

97%

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经验公式(希尔记法):
C6H4F2O4S2
分子量:
242.22
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

97%

形式

solid

反应适用性

reaction type: click chemistry

mp

127-132 °C

SMILES字符串

O=S(C1=C(S(=O)(F)=O)C=CC=C1)(F)=O

InChI

1S/C6H4F2O4S2/c7-13(9,10)5-3-1-2-4-6(5)14(8,11)12/h1-4H

InChI key

DNXLZBKMVRTNHQ-UHFFFAOYSA-N

应用

Sulfonyl fluoride motif can be used as a connector for the assembly of -SO2- linked small molecules with proteins or nucleic acids. This new click chemistry approach through sulfates is a complimentary approach to using amides and phosphate groups as linkers.

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Skin Corr. 1B

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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This article details the latest progress in synthesizing alkylsulfonyl fluorides through different approaches that utilize photoredox catalysis, electrocatalysis, transition-metal catalysis, and organocatalysis. The alkylsulfonyl fluorides thus prepared could be utilized further in sulfur(VI) fluoride exchange (SuFEx) click reactions.

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