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方案
96%
mp
154-157 °C (lit.)
SMILES字符串
O=C1c2ccccc2Cc3ccccc13
InChI
1S/C14H10O/c15-14-12-7-3-1-5-10(12)9-11-6-2-4-8-13(11)14/h1-8H,9H2
InChI key
RJGDLRCDCYRQOQ-UHFFFAOYSA-N
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一般描述
Anthrone (a tricyclic aromatic ketone) on mixing with sulfuric acid forms anthrone reagent, which is widely used in the estimation of sugars. Anthrone shows an inhibitory effect on the peroxidation of linoleic acid. It undergoes Michael addition with cinnamaldehyde in the presence of proline or prolinol derivatives.
应用
Anthrone has been used in colorimetric anthrone assay. It may be used to prepare azomethines by reacting with amines.
法规信息
新产品
Antioxidant activity of anthraquinones and anthrone.
Yen GC, et al.
Food Chemistry, 70(4), 437-441 (2000)
The estimation of carbohydrates in plant extracts by anthrone.
Yemm EW and Willis AJ.
The Biochemical Journal, 57(3), 508-508 (1954)
Synthesis of azomethines of anthrone.
Nadkarny VV and Sanzgiri MN.
J. Ind. Chem. Soc., 67(6), 513-514 (1990)
Asymmetric organocatalytic anthrone additions to activated alkenes.
Zea A, et al.
Tetrahedron, 67(14), 2513-2529 (2011)
Jason M Crawford et al.
Nature, 461(7267), 1139-1143 (2009-10-23)
Polyketides are a class of natural products with diverse structures and biological activities. The structural variability of aromatic products of fungal nonreducing, multidomain iterative polyketide synthases (NR-PKS group of IPKSs) results from regiospecific cyclizations of reactive poly-beta-keto intermediates. How poly-beta-keto
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