所有图片(5)
About This Item
线性分子式:
CH3OC6H4NH2
CAS号:
分子量:
123.15
Beilstein:
471556
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
99%
表单
solid
自燃温度
959 °F
沸点
240-243 °C (lit.)
mp
56-59 °C (lit.)
SMILES字符串
COc1ccc(N)cc1
InChI
1S/C7H9NO/c1-9-7-4-2-6(8)3-5-7/h2-5H,8H2,1H3
InChI key
BHAAPTBBJKJZER-UHFFFAOYSA-N
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应用
在存在金催化剂的条件下，对茴香胺可进行有氧氧化，形成芳族偶氮化合物。
对茴香胺可用于：
对茴香胺可用于：
- 在手性Bronsted酸催化下非对映选择性和对映选择性合成CF3-取代的偶氮啶。
- 在Yb(OTf)3催化下，通过与乙醛酸乙酯和乙炔基（苯基）硒烷的多组分Povarov反应，制备4-有机硒基喹啉。
- 作为分两步合成3-氟-6-甲氧基喹啉的原料。,
- 以三氟甲磺酸银(I)为催化剂，通过与末端炔烃和二乙基甲酰基膦酸酯水合物反应制备N-PMP保护的α-氨基炔丙基膦酸酯。
警示用语：
Danger
危险分类
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Carc. 1B - STOT RE 2
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
251.6 °F - closed cup
闪点(°C)
122 °C - closed cup
法规信息
危险化学品
非剧毒-急性毒性1
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Ytterbium (III)-catalyzed three-component reactions: synthesis of 4-organoselenium-quinolines
de Oliveira IM
New. J. Chem., 41(18), 9884-9888 (2017)
Dima A Sabbah et al.
Medicinal chemistry (Shariqah (United Arab Emirates)), 14(7), 695-708 (2018-04-14)
Phosphoinositide 3-kinase α (PI3Kα) is an attractive target for anticancer drug design. Target compounds were designed to probe the significance of alcohol and imine moieties tailored on a benzoin scaffold to better understand the structure activity relation (SAR) and improve
Noël Tenyang et al.
Food chemistry, 221, 1308-1316 (2016-12-17)
The aim of this study was to determine the effect of boiling and roasting on the proximate, lipid oxidation, fatty acid profile and mineral content of two sesame seeds varieties. The proximate composition was significantly affected (P<0.05) during treatments. The
Chiral Bronsted acid-catalyzed diastereo-and enantioselective synthesis of CF3-substituted aziridines
Chai Z, et al.
Chemical Communications (Cambridge, England), 48(76), 9471-9473 (2012)
A Facile Two-Step Synthesis of 3-Fluoro-6-methoxyquinoline
Li B, et al.
Organic Process Research & Development, 12(6), 1273-1275 (2008)
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