A30702
烯丙基氯
reagent grade, 98%
别名:
3-氯-1-丙烯, 氯丙烯
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线性分子式:
CH2=CHCH2Cl
化学文摘社编号:
分子量:
76.52
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-457-6
Beilstein/REAXYS Number:
635704
MDL number:
产品名称
烯丙基氯, reagent grade, 98%
InChI key
OSDWBNJEKMUWAV-UHFFFAOYSA-N
InChI
1S/C3H5Cl/c1-2-3-4/h2H,1,3H2
SMILES string
ClCC=C
grade
reagent grade
vapor density
2.6 (vs air)
vapor pressure
20.58 psi ( 55 °C)
5.71 psi ( 20 °C)
assay
98%
form
liquid
expl. lim.
11.2 %
refractive index
n20/D 1.414 (lit.)
bp
44-46 °C (lit.)
mp
−130 °C (lit.)
density
0.939 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Other Notes
货号A30702-4X1L的产品即将停产。请订购A30702-1L单瓶装，因为其物理参数与上述产品本质相同。
Application
氯丙烯可用作反应剂：
- 通过原位生成的苯炔的烯丙基炔基化反应得到1-烯丙基-2-炔基苯衍生物。
- 使用钌催化剂与脂肪酸甲酯反应生成α,ω-双官能中间体。
- 通过Sn/I2催化的羰基化合物的Barbier烯丙基反应制备高烯丙醇化合物。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Muta. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
target_organs
Nervous system,Liver,Kidney, Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
-25.6 °F
flash_point_c
-32 °C
ppe
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
此项目有
Airong Xu et al.
Polymers, 11(5) (2019-05-15)
Cellulose is the most abundant natural biopolymer, with unique properties such as biodegradability, biocompability, nontoxicity, and so on. However, its extensive application has actually been hindered, because of its insolubility in water and most solvents. Herein, highly efficient cellulose solvents
Airong Xu et al.
Scientific reports, 9(1), 11518-11518 (2019-08-10)
The utilization of cellulose in industrial applicat is of great significance to sustainable development of human society and reducing dependence on dwindling fossil resources. Nevertheless, this utilization of cellulose has actually been limited due to its insolubilization. Here, novel solvents
Palladium-Catalyzed Allylalkynylation of Benzynes: A Highly Efficient Route to Substituted 1-Allyl-2-alkynylbenzenes
Jeganmohan M and Cheng C-H
Organic Letters, 6(16), 2821-2824 (2004)
Sn/I2 Mediated allylation of carbonyl compounds with allyl (crotyl) halide in water
Zhou Y, et al.
ARKIVOC (Gainesville, FL, United States), 11(1), 142-153 (2008)
Cross-metathesis reactions of allyl chloride with fatty acid methyl esters: Efficient synthesis of a, ?-difunctional chemical intermediates from renewable raw materials.
Jacobs T, et al.
Applied Catalysis A: General, 353(1), 32-35 (2009)
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