推荐产品
蒸汽密度
4.2 (vs air)
质量水平
产品线
ReagentPlus®
方案
99%
表单
liquid
自燃温度
554 °F
包含
≤1000 ppm propylene oxide as stabilizer
expl. lim.
7.3 %
折射率
n20/D 1.469 (lit.)
沸点
70-71 °C (lit.)
mp
−119 °C (lit.)
密度
1.398 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
BrCC=C
InChI
1S/C3H5Br/c1-2-3-4/h2H,1,3H2
InChI key
BHELZAPQIKSEDF-UHFFFAOYSA-N
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应用
烯丙基溴可作为制备以下物质的反应剂:
- 在路易酸的作用下通过各种腈的 Barbier 型烯丙基化制备烯丙基酮。
- 使用锌粉作为催化剂,与醛类或酮 类反应制备高烯丙醇。
- 通过氢化银团簇还原 C-C 键偶联制备 1,5-己二烯。
法律信息
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语:
Danger
危险分类
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Muta. 1B - Skin Corr. 1B
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
30.2 °F - closed cup
闪点(°C)
-1 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Gas-phase synthesis of [Ag4H]+ and its mediation of the C-C coupling of allyl bromide
Angewandte Chemie (International Edition in English), 44(5), 728-731 (2005)
Facile and efficient synthesis of homoallylic alcohols using allyl bromide and commercial zinc dust
Tetrahedron Letters, 36(27), 4885-4888 (1995)
Materials (Basel, Switzerland), 13(11) (2020-06-11)
The superior ability of thiiranes (episulfides) to undergo ring-opening polymerization (ROP) in the presence of anionic initiators allows the preparation of chemically stable polysulfide homopolymers. Incorporation of elemental sulfur (S8) by copolymerization below the floor temperature of S8 permits the
Synthesis of allyl ketone via Lewis acid promoted Barbier-type reaction
Tetrahedron Letters, 41(45), 8803-8806 (2000)
Design and synthesis of modular oxazoline ligands for the enantioselective chromium-catalyzed addition of allyl bromide to ketones.
Journal of the American Chemical Society, 129(10), 2752-2753 (2007-02-21)
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