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安全信息

938742

Sigma-Aldrich

RuPhos Pd G6 Br

greener alternative

别名:

(RuPhos)Pd(p-CF3C6H4)(Br), 2-Dicyclohexylphosphino-2′,6′-diisopropoxybiphenyl Pd G6 Br

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About This Item

经验公式（希尔记法）:
C37H47BrF3O2PPd
CAS号:
2422128-43-4
分子量:
798.06
UNSPSC代码:
12352100
NACRES:
NA.21

表单

powder

质量水平

100

反应适用性

reaction type: Cross Couplings
reagent type: catalyst

环保替代产品特性

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

颜色

very faintly yellow

官能团

phosphine

环保替代产品分类

Aligned

SMILES字符串

Br[Pd](C1=CC=C(C=C1)C(F)(F)F)P(C2=C(C3=C(C=CC=C3OC(C)C)OC(C)C)C=CC=C2)(C4CCCCC4)C5CCCCC5

InChI

InChI=1S/C30H43O2P.C7H4F3.BrH.Pd/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25;8-7(9,10)6-4-2-1-3-5-6;;/h11-13,18-25H,5-10,14-17H2,1-4H3;2-5H;1H;/q;;;+1/p-1

InChI key

IYBINOQILDORLG-UHFFFAOYSA-M

相关类别

一般描述

RuPhos Pd G6 is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

特点和优势

For feature and benefits, please visit the technical article on Buchwald G6 Precatalysts.

相关产品

产品编号
说明
价格

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCV9282

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商品

Buchwald G6 Precatalysts: Oxidative Addition Complexes

Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.

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