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Merck
CN

935905

氟代碳酸乙烯酯

greener alternative

Technipur®, 99% (GC)

别名:

4-氟-1,3-二氧戊环-2-酮, FEC

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经验公式(希尔记法):
C3H3FO3
化学文摘社编号:
分子量:
106.05
UNSPSC Code:
26111700
NACRES:
NA.21
MDL number:
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产品名称

氟代碳酸乙烯酯, Technipur®, 99% (GC)

InChI

1S/C3H3FO3/c4-2-1-6-3(5)7-2/h2H,1H2

SMILES string

FC1COC(=O)O1

InChI key

SBLRHMKNNHXPHG-UHFFFAOYSA-N

assay

99% (GC)

form

solid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

bp

212 °C

mp

18-23 °C

density

1.485 g/cm3

application(s)

battery manufacturing

greener alternative category

storage temp.

2-8°C

Quality Level

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Application

Fluoroethylene carbonate (FEC) is extensively used as a film-forming electrolyte additive in lithium-ion batteries, where it facilitates the formation of a stable, lithium fluoride (LiF)-rich solid electrolyte interphase (SEI); which is insoluble in the electrolyte; in turn increasing the cycling efficiecny and discharge capacity retention of the secondary battery. Experiments concluded that use of fluorinated solvents or other performance additives such as FEC in the electrolyte can improve the low temperature performance, oxidation resistance, flame retardancy and wettability of the electrode. In another experiment, it has been found that the freestanding Si-carbon nanotubes (CNTs) composite paper anodes for Li-ion batteries achieve higher specific capacity and better capacity retention in terms of long-term cycling when FEC (10 wt%) is used as an additive.

Features and Benefits

  • Fluoroethylene carbonate (FEC), Technipur® is highly stable under electrochemical conditions, compatible with battery components for R&D activities, and ensures batch to batch reproducibility.
  • Large sized pre-packs tailored to your needs
  • Scalable supply chain for your manufacturing needs
  • Inventory availability is maintained for rapid delivery

General description

Fluoroethylene carbonate (FEC), Technipur®is a fluorinated cyclic carbonate, that comes in powder/crystal or chunk form with white in color. It has a purity of ≥99% and is designed to address R&D activities in the ongoing development and optimization of high-performance batteries. It is soluble in many organic solvents such as dimethyl carbonate (DMC), ethylene carbonate (EC), and diethyl carbonate (DEC). For smaller SKUs, visit 757349

We are committed to bringing you Greener Alternative Products, which belongs to one of the four categories of greener alternatives. Fluoroethylene carbonate is an enabling product, used as an electrolyte additive and is helpful to improve the performance of batteries, thus has been enhanced for energy efficiency. Click here for more information.

Legal Information

"Technipur is a registered trademark of Merck KGaA, Darmstadt, Germany"
Technipur is a registered trademark of Merck KGaA, Darmstadt, Germany

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Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1

存储类别

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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分析证书(COA)

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Understanding fluoroethylene carbonate and vinylene carbonate based electrolytes for Si anodes in lithium ion batteries with NMR spectroscopy
Yanting J, et al.
Journal of the American Chemical Society, 140(31), 9854-9867 (2018)
Understanding the thermal instability of fluoroethylene carbonate in LiPF6-based electrolytes for lithium ion batteries
Kim K, et al.
Electrochimica Acta, 225, 358-368 (2017)
Fluoroethylene carbonate electrolyte and its use in lithium ion batteries with graphite anodes
McMillan R, et al.
Journal of Power Sources, 81, 20-26 (1999)
A new insight into the content effect of fluoroethylene carbonate as a film forming additive for lithium-ion batteries
Zhao X, et al.
International Journal of Electrochemical Science, 10, 2515-2534 (2015)
Electrochemical characteristics of amorphous silicon thin film electrode with fluoroethylene carbonate additive
Kim J S, et al.
Current Applied Physics, 14, 596-602 (2014)

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