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安全信息

935719

Sigma-Aldrich

硝酸钴(II) 六水合物

greener alternative

≥99.9% trace metals basis

别名:

硝酸亚钴, 硝酸亚钴 六水合物, 硝酸,钴(II)盐

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About This Item

线性分子式:
Co(NO3)2 · 6H2O
CAS号:
分子量:
291.03
MDL编号:
UNSPSC代码:
12352302
NACRES:
NA.21

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等级

for analytical purposes

质量水平

方案

≥99.9% trace metals basis

表单

powder, crystals or granules (Chunks)

环保替代产品特性

Design for Energy Efficiency
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sustainability

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颜色

faint red to very dark red

mp

55 °C (lit.)

溶解性

soluble, clear to slightly hazy

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239267203106230375
solubility

soluble, clear to slightly hazy

solubility

-

solubility

-

solubility

-

assay

≥99.9% trace metals basis

assay

≥98%, 98.0-102.0%

assay

99.999% trace metals basis

assay

98%

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

100

mp

55 °C (lit.)

mp

55 °C (lit.)

mp

55 °C (lit.)

mp

55 °C (lit.)

greener alternative product characteristics

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greener alternative product characteristics

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greener alternative product characteristics

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greener alternative product characteristics

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一般描述

Cobalt(II)nitrate hexahydrate is red solid which is soluble in water and polar solvents. It is also known as hexaaquacobalt(II) nitrate consists of [Co(OH2)6]2+ and [NO3]ions.
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应用

Cobalt(II) nitrate hexahydrate, has been widely used for the synthesis of Cobalt oxide nanoparticles and cobalt containing compounds. For Example:Cobalt(II) nitrate hexahydrate is used to synthesize cobalt-cobalt oxide/N-doped carbon hybrids, which are then used as hydrogen evolution reaction (HER) or superior oxygen evolution reaction (OER) catalysts in water splitting.[1]

It has also been used as a primary precursor material in the synthesis of Co3O4 nanocrystals in various shapes such as nanosheets, nanocubes, and nanobelts as a catalyst for methane combustion.[2]

Furthermore, the reaction of Cobalt(II) nitrate hexahydrate with Nickel(II) nitrate hexahydrate produces Nickel-cobalt layered double hydroxide nanosheets in presence of methanol and CTAB, which is used as a high-performance electrocatalyst for oxygen evolution.[3]

In addition, Cobalt(II) nitrate hexahydrate precursor powder is calcined to produce Co3O4 nanotubes using the template synthesis method. The Co3O4 nano-tubes, nanorods, and nanoparticles that have been created are used in gas sensing systems and as anode materials for Li-ion batteries[4]

Cobalt hydroxide and layered double hydroxides (CH@LDH) have been synthesized using Cobalt(II)nitrate hexahydrate as a sulfur host for lithium–sulfur batteries.[5]

It is well studied that, Cobalt(II) nitrate hexahydrate is used as a heterogeneous catalyst Co/SiO2 with Silica support, for Fischer−Tropsch Synthesis.[6]

Cobalt(II) Nitrate Hexahydrate is also used as a catalyst for the synthesis of 5-Carboxanilide-dihydropyrimidinone derivatives by the condensation reaction of acetoacetanilide, aldehyde and urea/thiourea.[7]

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Muta. 2 - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 2 Inhalation

靶器官

Lungs

储存分类代码

5.1B - Oxidizing hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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    分析证书(COA)

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    访问文档库

    Co3O4 Nanomaterials in Lithium-Ion Batteries and Gas Sensors
    Li W Y, et al.
    Advanced Functional Materials , 15, 851-857 (2005)
    Nickel?cobalt layered double hydroxide nanosheets as high-performance electrocatalyst for oxygen evolution reaction
    Jiang J, et al.
    Journal of Power Sources, 278, 445-451 (2015)
    Fundamentals of melt infiltration for the preparation of supported metal catalysts. The case of Co/SiO2 for Fischer-Tropsch synthesis
    Eggenhuisen T M, et al.
    Journal of the American Chemical Society, 132, 18318-18325 (2010)
    In situ cobalt-cobalt oxide/N-doped carbon hybrids as superior bifunctional electrocatalysts for hydrogen and oxygen evolution
    Jin H, et al.
    Journal of the American Chemical Society, 137, 2688-2694 (2015)
    Double-Shelled Nanocages with Cobalt Hydroxide Inner Shell and Layered Double Hydroxides Outer Shell as High-Efficiency Polysulfide Mediator for Lithium-Sulfur Batteries
    Zhang J, et al.
    Angewandte Chemie (International ed. in English), 55, 3982-3986 (2016)

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