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一般描述
Ring opening metathesis polymerization (ROMP) monomers are attractive building block for advanced polymeric materials in the biomedical field. (5E)-2,2-Diethyl-1,3-dioxa-2-silacyclohept-5-ene, or the silyl ether based ROMP monomer EtSi, is a bifunctional cyclic olefin that can be used to synthesize a variety of macromolecules and polymers with diverse compositions and complex structures. EtSi can copolymerize with a variety of norbornene derivatives including small molecules and macromolecules, enabling the formation of backbone-degradable copolymers that can be used in a variety of biomedical applications. The ROMP polymerization method is superior as it permits the tailorability of the resulting polymer material.
应用
Synthesis of advanced polymeric materials for biomedical applications including:
- drug delivery
- molecular imaging
- self assembly
- hydrogels
- medical device coatings
- stimuli responsive material
特点和优势
- Copolymerize efficiency with a wide variety of norbornene-based (macro)monomers
- Controlled ROMP polymerization
- Silyl ether substitute can be tuned to control degradation
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
Peyton Shieh et al.
Nature chemistry, 11(12), 1124-1132 (2019-10-30)
Ring-opening metathesis polymerization of norbornene-based (macro)monomers is a powerful approach for the synthesis of macromolecules with diverse compositions and complex architectures. Nevertheless, a fundamental limitation of polymers prepared by this strategy is their lack of facile degradability, limiting their utility
Banruo Huang et al.
Journal of the American Chemical Society, 143(43), 17920-17925 (2021-10-23)
Materials capable of degradation upon exposure to light hold promise in a diverse range of applications including biomedical devices and smart coatings. Despite the rapid access to macromolecules with diverse compositions and architectures enabled by ring-opening metathesis polymerization (ROMP), a
Scott C Radzinski et al.
Macromolecular rapid communications, 37(7), 616-621 (2016-02-06)
Bottlebrush polymers are synthesized using a tandem ring-opening polymerization (ROP) and ring-opening metathesis polymerization (ROMP) strategy. For the first time, ROP and ROMP are conducted sequentially in the same pot to yield well-defined bottlebrush polymers with molecular weights in excess
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