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Merck
CN

934046

Sigma-Aldrich

Ethyl 1,1,2,2-tetrafluoroethyl ether

greener alternative

≥99%, anhydrous, battery grade

别名:

1,1,2,2-Tetrafluoroethyl ethyl ether, 1-Ethoxy-1,1,2,2-tetrafluoroethane, ETFE, HFE 374

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About This Item

经验公式(希尔记法):
C4H6F4O
CAS号:
分子量:
146.08
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.21

等级

battery grade

质量水平

方案

≥99%

表单

liquid

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

杂质

≤100 ppm HF
≤200 ppm H2O

沸点

58 °C

mp

-86 °C (lit.)

密度

1.21 g/mL

应用

battery manufacturing

环保替代产品分类

SMILES字符串

FC(F)(OCC)C(F)F

InChI

1S/C4H6F4O/c1-2-9-4(7,8)3(5)6/h3H,2H2,1H3

InChI key

HBRLMDFVVMYNFH-UHFFFAOYSA-N

一般描述

Ethyl 1,1,2,2-tetrafluoroethyl ether (ETFE) is a fluorinated linear ether that has several key properties that make it useful in batteries. First, ETFE is miscible with many polar organic solvents used in electrolyte formulations, which improves the ionic conductivity of the battery. Additionally, ETFE has a relatively low viscosity (486 mPa•s at 23 °C) and a low boiling point (58 °C), which make it a versatile diluent for low-temperature applications. Our battery grade ETFE is manufactured with high purity and low trace impurities of water and acid.
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应用

Ethyl 1,1,2,2-tetrafluoroethyl ether (ETFE) is a highly effective additive in lithium-ion batteries and sodium-ion batteries for improving battery performance, increasing safety, and reducing flammability. ETFE is a versatile co-solvent with high miscibility, which allows it to be blended with other solvents to achieve high ionic conductivities. It is also a good SEI-forming electrolyte additive, stabilizing the Na electrode surface and enhancing the stability of high-voltage batteries. ETFE is particularly useful as an electrolyte co-solvent in lithium-sulfur (Li-S) batteries. Studies have shown that ETFE-containing electrolytes improve the stability of the electrolyte/anode interface and enhance the cycling, rate, and self-discharging of the Li-S cell more than glyme-based cosolvents or unblended solvents. With its unique properties and proven effectiveness, battery-grade ETFE is an excellent choice for manufacturers looking to create high-performing, reliable, and safe lithium-ion and sodium-ion batteries.

象形图

Flame

警示用语:

Danger

危险声明

危险分类

Flam. Liq. 2

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

5.0 °F

闪点(°C)

-15 °C

法规信息

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访问文档库

Synthesis and electrochemical properties of partially fluorinated ether solvents for lithium sulfur battery electrolytes,
Yue , et al.
Journal of Power Sources, 401, 271-277 (2018)
Lithium/sulfur batteries with mixed liquid electrolytes based on ethyl 1,1,2,2-tetrafluoroethyl ether,
Hai, et al.
Electrochimica Acta, 161, 55-62 (2015)
Nasim Azimi et al.
ACS applied materials & interfaces, 7(17), 9169-9177 (2015-04-14)
A high performance Li-S battery with novel fluoroether-based electrolyte was reported. The fluorinated electrolyte prevents the polysulfide shuttling effect and improves the Coulombic efficiency and capacity retention of the Li-S battery. Reversible redox reaction of the sulfur electrode in the

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