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Merck
CN

934046

Ethyl 1,1,2,2-tetrafluoroethyl ether

greener alternative

≥99%, anhydrous, battery grade

别名:

1,1,2,2-Tetrafluoroethyl ethyl ether, 1-Ethoxy-1,1,2,2-tetrafluoroethane, ETFE, HFE 374

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关于此项目

经验公式(希尔记法):
C4H6F4O
化学文摘社编号:
分子量:
146.08
UNSPSC Code:
12352100
NACRES:
NA.21
MDL number:
PubChem Substance ID:
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产品名称

Ethyl 1,1,2,2-tetrafluoroethyl ether, ≥99%, anhydrous, battery grade

SMILES string

FC(F)(OCC)C(F)F

InChI

1S/C4H6F4O/c1-2-9-4(7,8)3(5)6/h3H,2H2,1H3

InChI key

HBRLMDFVVMYNFH-UHFFFAOYSA-N

grade

battery grade

assay

≥99%

form

liquid

greener alternative product characteristics

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sustainability

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impurities

≤100 ppm HF
≤200 ppm H2O

bp

58 °C

mp

-86 °C (lit.)

density

1.21 g/mL

application(s)

battery manufacturing

greener alternative category

Quality Level

General description

Ethyl 1,1,2,2-tetrafluoroethyl ether (ETFE) is a fluorinated linear ether that has several key properties that make it useful in batteries. First, ETFE is miscible with many polar organic solvents used in electrolyte formulations, which improves the ionic conductivity of the battery. Additionally, ETFE has a relatively low viscosity (486 mPa•s at 23 °C) and a low boiling point (58 °C), which make it a versatile diluent for low-temperature applications. Our battery grade ETFE is manufactured with high purity and low trace impurities of water and acid.
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Application

Ethyl 1,1,2,2-tetrafluoroethyl ether (ETFE) is a highly effective additive in lithium-ion batteries and sodium-ion batteries for improving battery performance, increasing safety, and reducing flammability. ETFE is a versatile co-solvent with high miscibility, which allows it to be blended with other solvents to achieve high ionic conductivities. It is also a good SEI-forming electrolyte additive, stabilizing the Na electrode surface and enhancing the stability of high-voltage batteries. ETFE is particularly useful as an electrolyte co-solvent in lithium-sulfur (Li-S) batteries. Studies have shown that ETFE-containing electrolytes improve the stability of the electrolyte/anode interface and enhance the cycling, rate, and self-discharging of the Li-S cell more than glyme-based cosolvents or unblended solvents. With its unique properties and proven effectiveness, battery-grade ETFE is an excellent choice for manufacturers looking to create high-performing, reliable, and safe lithium-ion and sodium-ion batteries.

pictograms

Flame

signalword

Danger

hcodes

Hazard Classifications

Flam. Liq. 2

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

5.0 °F

flash_point_c

-15 °C

法规信息

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分析证书(COA)

Lot/Batch Number

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Lithium/sulfur batteries with mixed liquid electrolytes based on ethyl 1,1,2,2-tetrafluoroethyl ether,
Hai, et al.
Electrochimica Acta, 161, 55-62 (2015)
Synthesis and electrochemical properties of partially fluorinated ether solvents for lithium sulfur battery electrolytes,
Yue , et al.
Journal of Power Sources, 401, 271-277 (2018)
Nasim Azimi et al.
ACS applied materials & interfaces, 7(17), 9169-9177 (2015-04-14)
A high performance Li-S battery with novel fluoroether-based electrolyte was reported. The fluorinated electrolyte prevents the polysulfide shuttling effect and improves the Coulombic efficiency and capacity retention of the Li-S battery. Reversible redox reaction of the sulfur electrode in the

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