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Merck
CN

933961

Sigma-Aldrich

1,1,2,2-Tetrafluoroethyl 2,2,3,3-tetrafluoropropylether

greener alternative

≥99%, <=10 ppm acid, battery grade

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别名:
1,1,2,2-Tetrafluoro-3-(1,1,2,2-tetrafluoroethoxy)propane, HFE-458, TTE
经验公式(希尔记法):
C5H4F8O
CAS号:
分子量:
232.07
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.21

等级

battery grade

质量水平

描述

Application: Battery manufacturing

检测方案

≥99%

形式

liquid

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

杂质

≤10 ppm Acid
≤100 ppm Non-volatile residue
≤750 ppm H2O

bp

92 °C

密度

1.54 g/mL

应用

battery manufacturing

环保替代产品分类

一般描述

Our 1,1,2,2-tetrafluoroethyl 2,2,3,3-tetrafluoropropylether (TTE) is a high-purity, battery-grade fluorinated ether commonly used as an electrolyte solvent in lithium-ion batteries (LIBs). It is a clear liquid with a boiling point of 92 °C that is miscible with many polar organic solvents, including carbonates typically used in battery electrolytes. Our TTE is produced to meet the high standards of battery-grade purity, ensuring a minimum purity level of 99%, and is carefully purified to become anhydrous and acid-free, making it a reliable choice for battery applications.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more information.

应用

1,1,2,2-Tetrafluoroethyl 2,2,3,3-tetrafluoropropylether (TTE) is a highly versatile fluorinated ether that finds its use as a co-solvent and additive in a range of battery systems, including lithium-sulfur batteries (LSBs) and lithium-ion batteries (LiBs). In LSBs, TTE plays a crucial role in reducing the solubility of intermediate lithium polysulfides, thereby preventing the polysulfide shuttle (PSS) effect and improving battery performance. Recent research suggests that TTE can also lead to the formation of a compact and uniform surface layer on the lithium anode when used as an additive, which improves the efficiency and stability of Li-S batteries. In LiBs, TTE acts as a cosolvent, reducing the viscosity of the electrolyte and enabling the use of lower concentrations of lithium salt without compromising ionic conductivity. Additionally, TTE has been shown to help form a stable, conductive solid electrolyte interphase (SEI) on both graphite anodes and NMC cathodes, thereby improving the overall electrochemical performance of the battery.

象形图

Flame

警示用语:

Warning

危险声明

危险分类

Flam. Liq. 3

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

法规信息

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Fluoro-Ether as a Bifunctional Interphase Electrolyte Additive with Graphite/LiNi0.5Co0.2Mn0.3O2 Full Cell
[3]Heng, et al.
ACS Applied Energy Materials, 2, 6404-6416 (2019)
Synthesis and electrochemical properties of partially fluorinated ether solvents for lithiumsingle bondsulfur battery electrolytes
Yue Zheng, et al.
Journal of Power Sources, 401, 271-277 (2018)
Partially Fluorinated Ether as an Electrolyte Additive to Modify Electrode Surface and Suppress Dissolution of Polysulfides in Li-S Batteries
Qian, Feng
Electrochemical Energy Technology , 4 (2018)

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