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安全信息

932426

Sigma-Aldrich

4,4′,4′′-Tris(N-(naphthalen-2-yl)-N-phenyl-amino)-triphenylamine

≥99% (HPLC)

别名:

4,4′,4′′-Tris[2-naphthyl(phenyl)amino]triphenylamine, 2T-NATA, 2-TNATA, 2TNATA

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About This Item

经验公式（希尔记法）:
C66H48N4
CAS号:
185690-41-9
分子量:
897.11
MDL编号:
MFCD01310662
UNSPSC代码:
12352116
NACRES:
NA.23
方案:
≥99% (HPLC)
等级:
sublimed grade
溶解性:
THF: soluble
chloroform: soluble

等级

sublimed grade

质量水平

100

描述

μh ≈ 3.0 x 10-6 cm2 V−1 s−1

方案

≥99% (HPLC)

缺失

0.5% TGA, > 350 °C (weight loss)

mp

247 °C

溶解性

THF: soluble
chloroform: soluble

荧光

λem 490 nm±10 nm in THF

轨道能量

HOMO 5.1 eV 
LUMO 2.2 eV 

λ

in THF

紫外吸收

λ: 326 nm±5 nm Amax

SMILES字符串

c1ccc(cc1)N(c2ccc(cc2)N(c3ccc(cc3)N(c4ccccc4)c5ccc6ccccc6c5)c7ccc(cc7)N(c8ccccc8)c9ccc%10ccccc%10c9)c%11ccc%12ccccc%12c%11

InChI

1S/C66H48N4/c1-4-22-55(23-5-1)68(64-31-28-49-16-10-13-19-52(49)46-64)61-40-34-58(35-41-61)67(59-36-42-62(43-37-59)69(56-24-6-2-7-25-56)65-32-29-50-17-11-14-20-53(50)47-65)60-38-44-63(45-39-60)70(57-26-8-3-9-27-57)66-33-30-51-18-12-15-21-54(51)48-66/h1-48H

InChI key

KDOQMLIRFUVJNT-UHFFFAOYSA-N

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相关类别

应用

4,4′,4′′-Tris(N-(naphthalen-2-yl)-N-phenyl-amino)-triphenylamine can be used in various applications in organic electronics and materials chemistry such as organic Light-Emitting Diodes (OLEDs), organic Photovoltaics(OPVs), organic Field-Effect Transistors (OFETs), dye-sensitized solar Cells(DSSCs), as a hole transport material. It can be utilized in the assembly of supramolecular structures or coordination polymers, offering opportunities for the design and synthesis of functional materials.
Injection Layer (HIL) in Organic Light Emitting Diode (OLED).

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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分析证书(COA)

Lot/Batch Number
MKCT1309

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Synthesis and electroluminescent properties of 9,10-diphenylanthracene containing 9H-carbazole derivatives for blue organic light-emitting diodes.
Lee S B, et al.
Synthetic Metals, 203, 174-179 (2015)
Beomjin Kim et al.
Journal of nanoscience and nanotechnology, 14(8), 6404-6408 (2015-05-06)
New hole injection materials for OLED based on phenothiazine were synthesized, and the electro-optical properties of synthesized materials were examined by through UV-Vis. and photoluminescence spectroscopy as well as cyclic voltammetry. 1-NDD-t-BPBP and 2-NDD-t-BPBP showed Tg of 180 and 177
Synthesis and electroluminescent properties of 9,10-diphenylanthracene containing 9H-carbazole derivatives for blue organic light-emitting diodes.
Lee S B, et al.
Synth. Meth. Organomet. Inorg. Chem., 203, 174-179 (2015)

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