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Merck
CN

932310

Sigma-Aldrich

氟化锂

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别名:
氟石
线性分子式:
LiF
CAS号:
分子量:
25.94
MDL编号:
UNSPSC代码:
12352302
NACRES:
NA.23

检测方案

≥99%

质量水平

bp

1681 °C

mp

845 °C (lit.)

溶解性

H2O: 2.9 g/L

密度

2.64 g/mL at 25 °C (lit.)

轨道能量

HOMO 14 eV 
LUMO 1.0 eV 

SMILES字符串

[Li+].[F-]

InChI

1S/FH.Li/h1H;/q;+1/p-1

InChI key

PQXKHYXIUOZZFA-UHFFFAOYSA-M

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应用

LiF can be used in thermoluminescent; perovskite light-emitting diodes; rechargeable batteries and MXenes applications. Lithium fluoride crystals are transparent to ultraviolet (UV) light and are used in UV optics. Lithium fluoride is used in the main route of fabrication of Mxenes by exfoliating MAX phases.

象形图

Skull and crossbones

警示用语:

Danger

危险分类

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

补充剂危害

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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Recent progress in LiF materials for safe lithium metal anode of rechargeable batteries: Is LiF the key to commercializing Li metal batteries?
Ko J, et al.
Ceramics International, 45(1), 30-49 (2019)
Bing Zhou et al.
ACS applied materials & interfaces, 12(4), 4895-4905 (2020-01-04)
Flexible, lightweight, robust, and multifunctional characteristics are greatly desirable for next-generation wearable electromagnetic interference (EMI) shielding materials. In this work, an alternating multilayered structure with robust polymer frame layers and directly contacted conducting layers was designed to prepare high-performance EMI
Mingfu He et al.
Proceedings of the National Academy of Sciences of the United States of America, 117(1), 73-79 (2019-12-19)
Lithium is the most attractive anode material for high-energy density rechargeable batteries, but its cycling is plagued by morphological irreversibility and dendrite growth that arise in part from its heterogeneous "native" solid electrolyte interphase (SEI). Enriching the SEI with lithium
Xiulin Fan et al.
Science advances, 4(12), eaau9245-eaau9245 (2018-12-28)
Solid-state electrolytes (SSEs) are receiving great interest because their high mechanical strength and transference number could potentially suppress Li dendrites and their high electrochemical stability allows the use of high-voltage cathodes, which enhances the energy density and safety of batteries.
Xiaolei Yang et al.
Nature communications, 9(1), 570-570 (2018-02-10)
Perovskite light-emitting diodes (LEDs) are attracting great attention due to their efficient and narrow emission. Quasi-two-dimensional perovskites with Ruddlesden-Popper-type layered structures can enlarge exciton binding energy and confine charge carriers and are considered good candidate materials for efficient LEDs. However

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