推荐产品
质量水平
方案
≥95%
表单
powder
mp
154-155 °C
储存温度
−20°C
SMILES字符串
O=C(C(NCC1=CC=CC=C1)=O)NC2=CC=C(C)C=C2C3=CC=CC=C3
InChI
1S/C22H20N2O2/c1-16-12-13-20(19(14-16)18-10-6-3-7-11-18)24-22(26)21(25)23-15-17-8-4-2-5-9-17/h2-14H,15H2,1H3,(H,23,25)(H,24,26)
InChI key
AWTLXLDETPWZRB-UHFFFAOYSA-N
应用
PMPBO is a ligand for the copper-catalyzed Ullman-Ma cross-coupling reaction.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
Yuntong Zhai et al.
The Journal of organic chemistry, 82(9), 4964-4969 (2017-04-22)
Diaryl formation is achieved by coupling phenols and (hetero)aryl halides under the catalysis of CuI/N,N'-bis(2-phenylphenyl) oxalamide (BPPO) or CuI/N-(2-phenylphenyl)-N'-benzyl oxalamide (PPBO) at 90 °C using DMF or MeCN as the solvent. Only 0.2-2 mol % CuI and ligand are required
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