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Merck
CN

925713

铂八乙基卟啉

≥97%

别名:

PtOEP, 铂(II) 2,3,7,8,12,13,17,18-八乙基-21H,23H-卟啉

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关于此项目

经验公式(希尔记法):
C36H44N4Pt
化学文摘社编号:
分子量:
727.84
UNSPSC Code:
12352103
NACRES:
NA.23
MDL number:
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产品名称

铂八乙基卟啉, ≥97%

InChI

1S/C36H44N4.Pt/c1-9-21-22(10-2)30-18-32-25(13-5)26(14-6)34(39-32)20-36-28(16-8)27(15-7)35(40-36)19-33-24(12-4)23(11-3)31(38-33)17-29(21)37-30;/h17-20H,9-16H2,1-8H3;/q-2;+2/b29-17-,30-18-,31-17-,32-18-,33-19-,34-20-,35-19-,36-20-;

SMILES string

CCc1c(CC)c2cc3c(CC)c(CC)c4cc5nc(cc6c(CC)c(CC)c(cc1n2)n6[Pt]n34)c(CC)c5CC

InChI key

WAODGUVBNLMTSF-XTPDIVBZSA-N

description

UV: 381, 501, 535 nm (in CHCl3)

assay

≥97%

form

powder or crystals

color

red

mp

>300 °C

λmax

649 nm (PL)

orbital energy

HOMO 5.3 eV 
LUMO 3.2 eV 

UV absorption

λ: 381 nm Amax
λ: 501 nm Amax
λ: 535 nm Amax

Quality Level

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Application

Platinum octaethylporphyrin (PtOEP) is used as a red triplet emitting material with high external quantum yields for organic light-emitting diodes (OLEDs). It can be utilized as the active component in chemical sensors or biosensors research. The ability of these compounds to form ordered structures makes them interesting candidates for molecular electronics, molecular magnets, and other advanced materials. 4) It is suitable to be used as a photosensitizer in photodynamic therapy.
Platinum octaethylporphyrin (PtOEP) may be used as a fluorescent dye in the fabrication of polymer- and silica-based oxygen sensors.
It is used as a red triplet emitting material with high external quantum yields for OLEDs. PtOEP is used as a dopant in host materials like CBP and Alq3. Its red emission is near 650 nm depending on host material and processing conditions.

存储类别

11 - Combustible Solids

wgk

WGK 3


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Organic Electroluminescent Sensor for Pressure Measurement.
Matsuda Y, et al.
Sensors, 12, 13899-13906 (2012)
A Prototype of a Volumetric Three-Dimensional Display Based on Programmable Photo-Activated Phosphorescence.
Dr Wan S, et al.
Angewandte Chemie (International Edition in English), 59, 8416-8420 (2020)
Photoelectrochemical Properties of Metalloporphyrins.
Kampas F J, et al.
Nature, 284, 40-42 (1980)
Highly efficient deep-red organic light-emitting diodes using exciplex-forming co-hosts and thermally activated delayed fluorescence sensitizers with extended lifetime.
Li D, et al.
Journal of Material Chemistry C, 7, 9531-9536 (2019)

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