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Merck
CN

925713

Sigma-Aldrich

铂八乙基卟啉

≥97%

别名:

PtOEP, 铂(II) 2,3,7,8,12,13,17,18-八乙基-21H,23H-卟啉

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About This Item

经验公式(希尔记法):
C36H44N4Pt
CAS号:
分子量:
727.84
MDL编号:
UNSPSC代码:
12352103
NACRES:
NA.23

描述

UV: 381, 501, 535 nm (in CHCl3)

质量水平

方案

≥97%

表单

powder or crystals

颜色

red

mp

>300 °C

λmax

649 nm (PL)

轨道能量

HOMO 5.3 eV 
LUMO 3.2 eV 

紫外吸收

λ: 381 nm Amax
λ: 501 nm Amax
λ: 535 nm Amax

SMILES字符串

CCc1c(CC)c2cc3c(CC)c(CC)c4cc5nc(cc6c(CC)c(CC)c(cc1n2)n6[Pt]n34)c(CC)c5CC

InChI

1S/C36H44N4.Pt/c1-9-21-22(10-2)30-18-32-25(13-5)26(14-6)34(39-32)20-36-28(16-8)27(15-7)35(40-36)19-33-24(12-4)23(11-3)31(38-33)17-29(21)37-30;/h17-20H,9-16H2,1-8H3;/q-2;+2/b29-17-,30-18-,31-17-,32-18-,33-19-,34-20-,35-19-,36-20-;

InChI key

WAODGUVBNLMTSF-XTPDIVBZSA-N

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应用

Platinum octaethylporphyrin (PtOEP) is used as a red triplet emitting material with high external quantum yields for organic light-emitting diodes (OLEDs). It can be utilized as the active component in chemical sensors or biosensors research. The ability of these compounds to form ordered structures makes them interesting candidates for molecular electronics, molecular magnets, and other advanced materials. 4) It is suitable to be used as a photosensitizer in photodynamic therapy.
Platinum octaethylporphyrin (PtOEP) may be used as a fluorescent dye in the fabrication of polymer- and silica-based oxygen sensors.
It is used as a red triplet emitting material with high external quantum yields for OLEDs. PtOEP is used as a dopant in host materials like CBP and Alq3. Its red emission is near 650 nm depending on host material and processing conditions.

储存分类代码

11 - Combustible Solids

WGK

WGK 3


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