92361
三甲基氯硅烷
≥98.0% (GC)
别名:
TMCS, Trimethylchlorosilane, 三甲基硅基氯
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关于此项目
线性分子式:
(CH3)3SiCl
化学文摘社编号:
分子量:
108.64
UNSPSC Code:
12352302
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-900-5
Beilstein/REAXYS Number:
1209232
MDL number:
产品名称
三甲基氯硅烷, ≥98.0% (GC)
InChI key
IJOOHPMOJXWVHK-UHFFFAOYSA-N
InChI
1S/C3H9ClSi/c1-5(2,3)4/h1-3H3
SMILES string
C[Si](C)(C)Cl
vapor density
3.7 (vs air)
vapor pressure
100 mmHg ( 25 °C)
assay
≥98.0% (GC)
form
liquid
autoignition temp.
752 °F
expl. lim.
6.4 %
refractive index
n20/D 1.387 (lit.)
bp
57 °C (lit.)
mp
−40 °C (lit.)
density
0.856 g/mL at 25 °C (lit.)
Quality Level
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Application
三甲基氯硅烷已被用于使玻璃表面硅烷化，以增强其疏水性。它可以与六甲基二硅氮烷一起使用，通过甲硅烷基化反应形成三甲基甲硅烷基醚来保护醇。还用于Fisher糖基化
General description
三甲基氯硅烷是一种氯-有机硅烷化合物，主要用于甲硅烷基化反应。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
-18.4 °F - closed cup
flash_point_c
-28 °C - closed cup
ppe
Faceshields, Gloves, Goggles
法规信息
危险化学品
此项目有
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations, 4, 261-261 (2014)
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Oh HJ, et al.
Polymer, 55(1), 235-247 (2014)
Use of organosilicon reagents as protective groups in organic synthesis.
Lalonde M & Chan TH.
Synthesis, 1985(09), 817-845 (1985)
Yuma Komata et al.
Chemistry, an Asian journal, 11(22), 3225-3233 (2016-10-21)
Alkoxychlorosilanes are scientifically and industrially important toward preparing silicone and silica as well as preparation of siloxane-based nanomaterials by stepwise reactions of Si-OR (R=alkyl) and Si-Cl groups. Intermolecular exchange of alkoxy and chloro groups between alkoxysilanes and chlorosilanes (functional group
Yongju Kwon et al.
Nature communications, 11(1), 3127-3127 (2020-06-21)
Magic-sized clusters (MSCs) can be isolated as intermediates in quantum dot (QD) synthesis, and they provide pivotal clues in understanding QD growth mechanisms. We report syntheses for two families of heterogeneous-atom-incorporated InP MSCs that have chlorine or zinc atoms. All
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