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923508

Sigma-Aldrich

(iPrMPhos)PdCl2

1:1 complex with CH2Cl2, ≥95%

别名:

1-Diadamantylphosphino-1′-diisopropylphosphinoferrocene palladium dichloride

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About This Item

经验公式（希尔记法）:
C36H52Cl2FeP2Pd
分子量:
779.92
UNSPSC代码:
12352103
NACRES:
NA.22

质量水平

100

方案

≥95%

表单

powder

反应适用性

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

SMILES字符串

ClCCl.[Cl-][Pd+2]1([Cl-])[P](C(C)C)(C(C)C)[C-]23[CH]4=[CH]5[CH]6=[CH]2[Fe+2]56789%1043[CH]=%11[CH]%10=[CH]9[C-]8([CH]%117)[P]1(C%12%13CC%14CC(CC(C%14)C%12)C%13)C%15%16CC%17CC(CC(C%17)C%15)C%16

InChI

InChI=1S/C25H34P.C11H18P.CH2Cl2.2ClH.Fe.Pd/c1-2-4-23(3-1)26(24-11-17-5-18(12-24)7-19(6-17)13-24)25-14-20-8-21(15-25)10-22(9-20)16-25;1-9(2)12(10(3)4)11-7-5-6-8-11;2-1-3;;;;/h1-4,17-22H,5-16H2;5-10H,1-4H3;1H2;2*1H;;/q2*-1;;;;2*+2/p-2

InChI key

JBKBIWGRUZQRBH-UHFFFAOYSA-L

相关类别

应用

(iPrMPhos)PdCl2 is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (iPrMPhos)PdCl2 can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling. Demonstrated Csp2-Csp3 couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).

Learn more about MPhos ligands and catalysts

其他说明

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp2–Csp3 Couplings

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价格

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

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YPhos ligands facilitate palladium-catalyzed coupling reactions of aryl chlorides under mild conditions with short reaction times.

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