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Merck
CN

923486

Sigma-Aldrich

(CyMPhos)PdCl2

complex with CH2Cl2

别名:

1-Diadamantylphosphino-1′-dicyclohexylphosphinoferrocene palladium dichloride

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About This Item

经验公式(希尔记法):
C42H60Cl2FeP2Pd
分子量:
860.04
UNSPSC代码:
12352101
NACRES:
NA.21

应用

(CyMPhos)PdCl2 is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (CyMPhos)PdCl2 can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling. Demonstrated Csp2-Csp3 couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).

Learn more about MPhos ligands and catalysts

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象形图

Health hazardExclamation mark

警示用语:

Warning

危险声明

危险分类

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp2?Csp3 Couplings
Xu, et al.
ACS Catalysis, 12, 5123?5135-5123?5135 (2022)

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