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表单
powder
质量水平
反应适用性
reagent type: catalyst
reaction type: Cross Couplings
SMILES字符串
[Pd]([PH](C5CCCCC5)(C4CCCCC4)c2c(ccc(c2c3c(cccc3C(C)C)C(C)C)C)C)(Br)c1ccc(cc1)C(=O)OCC[Si](C)(C)C
InChI
1S/C32H47P.C12H17O2Si.BrH.Pd/c1-22(2)28-18-13-19-29(23(3)4)31(28)30-24(5)20-21-25(6)32(30)33(26-14-9-7-10-15-26)27-16-11-8-12-17-27;1-15(2,3)10-9-14-12(13)11-7-5-4-6-8-11;;/h13,18-23,26-27H,7-12,14-17H2,1-6H3;5-8H,9-10H2,1-3H3;1H;
InChI key
TZDQPFRWRQKAKO-UHFFFAOYSA-N
应用
GPhos Pd G6 TES is a sixth generation (G6) Buchwald palladium precatalyst for cross-coupling reactions with demonstrated use for the room temperature coupling of primary amines with aryl halides.
Learn more about G6 Buchwald precatalysts
Learn more about G6 Buchwald precatalysts
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Elaine C Reichert et al.
Journal of the American Chemical Society, 145(6), 3323-3329 (2023-02-01)
We report a versatile and functional-group-tolerant method for the Pd-catalyzed C-N cross-coupling of five-membered heteroaryl halides with primary and secondary amines, an important but underexplored transformation. Coupling reactions of challenging, pharmaceutically relevant heteroarenes, such as 2-H-1,3-azoles, are reported in good-to-excellent
Development of an Aryl Amination Catalyst with Broad Scope Guided by Consideration of Catalyst Stability
Scott D, et al
Journal of the American Chemical Society, 142, 15027-15037 (2020)
商品
Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.
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