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Merck
CN
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安全信息

922854

Sigma-Aldrich

TpOx-Ph-m-CF3

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别名:
2,3,6,11,12-Pentakis(pentyloxy)-8-(3-(trifluoromethyl)phenyl)triphenyleno[1,2-d]oxazole
经验公式（希尔记法）:
C51H64F3NO6
CAS号:
2612025-76-8
分子量:
844.05
NACRES:
NA.23

描述

Polymorph crystalline phase: Solid, Discotic Liquid Crystal, Isotropic

质量水平

100

带隙

2.94 eV (Optical, Solution state)

转变温度

crystalline phase to discotic phase 132 °C (heating)
discotic phase to isotropic phase 243 °C (heating)

溶解性

soluble (THF > 1 mg /mL, MeCN < 0.4 mg/mL, DMSO < 0.27 mg/mL, DCM > 1 mg/mL)

λmax

271 nm in ethyl acetate

εmax

73,000 M-1cm-1 in ethyl acetate

荧光

λem 503 nm, quantum yield 0.48 (pSS(nm) = 232; Fluorescence lifetime (ns) = 7.07)

轨道能量

HOMO -5.47 eV (CV)
LUMO -2.52 eV (CV)

储存温度

−20°C

相关类别

一般描述

TpOx-Ph-m-CF3 is a UV excitable fluorescent material with a polycyclic aromatic donor-acceptor structure where the triphenoxazole core acts as a donor and the aromatic group on the two position of the oxazole (3-trifluoromethyl-phenyl) act as the acceptor group. The push-pull, donor-acceptor, structure facilitates intramolecular charge transfer in the excited state that results in a 232 nm emission Stokes Shift. This oxazole is also a photo-conducting Discotic Liquid Crystalline (DLC) material with mesophase transition onset temperature of 132 °C. It is designed for 355 nm and 405 nm excitation with emission at 503 nm with quantum yield of 0.48, high thermal, chemical and photostability. This luminescent compound has potential uses in fluorescent dye staining, organic electronic and photonics, and imaging applications.

应用

Fluorescent materials have a range of unique properties that allows for potential use in a range of applications:

  • Fluorescent dye staining
UV fluorescent materials can be used to dope polymer and resin composites, including 3D applications, and further identified using fluorescence emission.

  • Organic semiconductor for organic electronic and photonic applications
These organic discotic liquid crystals display columnar hexagonal mesophase, and were incorporated into OPV device as a hole transport layer and donor material. Similar compounds have been used in organic light emitting devices (OLEDs), organic photovoltaic device (OPVs) and organic field-effect transistor (OFETs) as hole transport material.

  • Multi-photon microscopy
These UV fluorescent materials have been used in multi-photon microscopy, showing remarkable image resolution relative to commercial fluorophores in the multiphoton microscopy imaging. By perfusing it into an ex-planted human liver, it was possible to observe fluorophore staining of the hepatocytes and T-cells in the liver vasculature. During the live liver imaging these probes have been shown to perfuse effectively in human tissue and emit brightly without significant cytotoxicity during the course of the experiment.

储存及稳定性

Store under nitrogen in the dark in the freezer (below 8 Celsius).

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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