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描述
Polymorph crystalline phase: Solid, Discotic Liquid Crystal, Isotropic
质量水平
带隙
2.94 eV (Optical, Solution state)
转变温度
crystalline phase to discotic phase 132 °C (heating)
discotic phase to isotropic phase 243 °C (heating)
溶解性
soluble (THF > 1 mg /mL, MeCN < 0.4 mg/mL, DMSO < 0.27 mg/mL, DCM > 1 mg/mL)
λmax
271 nm in ethyl acetate
εmax
73,000 M-1cm-1 in ethyl acetate
荧光
λem 503 nm, quantum yield 0.48 (pSS(nm) = 232; Fluorescence lifetime (ns) = 7.07)
轨道能量
HOMO -5.47 eV (CV)
LUMO -2.52 eV (CV)
储存温度
−20°C
一般描述
TpOx-Ph-m-CF3 is a UV excitable fluorescent material with a polycyclic aromatic donor-acceptor structure where the triphenoxazole core acts as a donor and the aromatic group on the two position of the oxazole (3-trifluoromethyl-phenyl) act as the acceptor group. The push-pull, donor-acceptor, structure facilitates intramolecular charge transfer in the excited state that results in a 232 nm emission Stokes Shift. This oxazole is also a photo-conducting Discotic Liquid Crystalline (DLC) material with mesophase transition onset temperature of 132 °C. It is designed for 355 nm and 405 nm excitation with emission at 503 nm with quantum yield of 0.48, high thermal, chemical and photostability. This luminescent compound has potential uses in fluorescent dye staining, organic electronic and photonics, and imaging applications.
应用
Fluorescent materials have a range of unique properties that allows for potential use in a range of applications:
- Fluorescent dye staining
- Organic semiconductor for organic electronic and photonic applications
- Multi-photon microscopy
储存及稳定性
Store under nitrogen in the dark in the freezer (below 8 Celsius).
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
商品
Triphenoxazoles exhibit tunable properties, liquid crystallinity, and potential for modification.
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