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![[Pd(IPr)(AN)Cl2] ≥95%](/deepweb/assets/sigmaaldrich/product/structures/377/159/7233feaa-ad18-45f3-bfb6-730ae44e4b82/640/7233feaa-ad18-45f3-bfb6-730ae44e4b82.png)
![[Pd(IPr)(3-CF3-AN)Cl2] ≥95%](/deepweb/assets/sigmaaldrich/product/structures/254/467/854da0d8-adc7-4d41-9729-d2d1db9bf915/640/854da0d8-adc7-4d41-9729-d2d1db9bf915.png)
![[Pd(IPr#)(3-CF3-AN)Cl2]](/deepweb/assets/sigmaaldrich/product/structures/355/543/15bba94c-804e-4ae9-bd88-49e2468ff01f/640/15bba94c-804e-4ae9-bd88-49e2468ff01f.png)
应用
Pd(IPr#)(AN)Cl2 is a Pd-catalyst that can be used in a broad range of reactions, including cross-coupling, C-H functionalization, electrophilic additions. NHC-Pd-aniline complexes of this type have many advantages, including higher reactivity in cross-coupling reactions than similar complexes using cinnamyl and pyridine throw-away ligands and simple reaction tunability through substituion of aniline ligand.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
法规信息
新产品
Qun Zhao et al.
Chemical science, 12(31), 10583-10589 (2021-08-28)
IPr (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) represents the most important NHC (NHC = N-heterocyclic carbene) ligand throughout the field of homogeneous catalysis. Herein, we report the synthesis, catalytic activity, and full structural and electronic characterization of novel, sterically-bulky, easily-accessible NHC ligands based
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