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安全信息

919365

Sigma-Aldrich

(MeBPI)Ni-OAc

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About This Item

经验公式（希尔记法）:
C22H19N5NiO2
分子量:
444.11
UNSPSC代码:
12352200
NACRES:
NA.22

应用

(MeBPI)Ni-OAc is a Ni catalyst developed in the Sevov lab for electrocatalytic cross-electrophile coupling reactions. When combined with a redox-active shuttle (918105), (MeBPI)Ni-OAc enables the reductive coupling of a wide range of aryl, heteroaryl, or vinyl bromides with primary or secondary alkyl bromides.

Product can be used with our Synlectro electrochemistry platform (ESYNTH001)

其他说明

General C(sp2)-C(sp3) Cross-Electrophile Coupling Reactions Enabled by Overcharge Protection of Homogeneous Electrocatalysts

相关产品

产品编号
说明
价格

918105

(MeBPI)2Ni, ≥95%

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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分析证书(COA)

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Blaise L Truesdell et al.
Journal of the American Chemical Society, 142(12), 5884-5893 (2020-03-03)
Cross-electrophile coupling (XEC) of alkyl and aryl halides promoted by electrochemistry represents an attractive alternative to conventional methods that require stoichiometric quantities of high-energy reductants. Most importantly, electroreduction can readily exceed the reducing potentials of chemical reductants to activate catalysts

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